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Bis­(methane­sulfonato-κO)(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N,N′,N′′,N′′′)tin(IV) chloro­form tris­olvate

In the crystal structure of the title compound, [Sn(C(44)H(28)N(4))(CH(3)O(3)S)(2)]·3CHCl(3), the Sn(IV) ion is located on an inversion center and is octa­hedrally coordinated. The porphyrin N atoms occupy the equatorial positions while the axial positions are occupied by the O atoms of the methane­...

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Autores principales: Singh, Atul P., Kim, Hee-Joon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344358/
https://www.ncbi.nlm.nih.gov/pubmed/22590124
http://dx.doi.org/10.1107/S1600536812015875
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author Singh, Atul P.
Kim, Hee-Joon
author_facet Singh, Atul P.
Kim, Hee-Joon
author_sort Singh, Atul P.
collection PubMed
description In the crystal structure of the title compound, [Sn(C(44)H(28)N(4))(CH(3)O(3)S)(2)]·3CHCl(3), the Sn(IV) ion is located on an inversion center and is octa­hedrally coordinated. The porphyrin N atoms occupy the equatorial positions while the axial positions are occupied by the O atoms of the methane­sulfonate anions. The phenyl rings make dihedral angles of 77.02 (13) and 87.89 (14)° with the porphyrin ring. Of the three solvent chloro­form mol­ecules, one is disordered over a twofold rotation axis. In the crystal a three-dimensional assembly is accomplished via C—H⋯O hydrogen bonds between the H atoms of the phenyl groups in the porphyrin ring and the O atoms of the methane­sulfonate ligands.
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spelling pubmed-33443582012-05-15 Bis­(methane­sulfonato-κO)(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N,N′,N′′,N′′′)tin(IV) chloro­form tris­olvate Singh, Atul P. Kim, Hee-Joon Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Sn(C(44)H(28)N(4))(CH(3)O(3)S)(2)]·3CHCl(3), the Sn(IV) ion is located on an inversion center and is octa­hedrally coordinated. The porphyrin N atoms occupy the equatorial positions while the axial positions are occupied by the O atoms of the methane­sulfonate anions. The phenyl rings make dihedral angles of 77.02 (13) and 87.89 (14)° with the porphyrin ring. Of the three solvent chloro­form mol­ecules, one is disordered over a twofold rotation axis. In the crystal a three-dimensional assembly is accomplished via C—H⋯O hydrogen bonds between the H atoms of the phenyl groups in the porphyrin ring and the O atoms of the methane­sulfonate ligands. International Union of Crystallography 2012-04-18 /pmc/articles/PMC3344358/ /pubmed/22590124 http://dx.doi.org/10.1107/S1600536812015875 Text en © Singh and Kim 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Singh, Atul P.
Kim, Hee-Joon
Bis­(methane­sulfonato-κO)(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N,N′,N′′,N′′′)tin(IV) chloro­form tris­olvate
title Bis­(methane­sulfonato-κO)(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N,N′,N′′,N′′′)tin(IV) chloro­form tris­olvate
title_full Bis­(methane­sulfonato-κO)(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N,N′,N′′,N′′′)tin(IV) chloro­form tris­olvate
title_fullStr Bis­(methane­sulfonato-κO)(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N,N′,N′′,N′′′)tin(IV) chloro­form tris­olvate
title_full_unstemmed Bis­(methane­sulfonato-κO)(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N,N′,N′′,N′′′)tin(IV) chloro­form tris­olvate
title_short Bis­(methane­sulfonato-κO)(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N,N′,N′′,N′′′)tin(IV) chloro­form tris­olvate
title_sort bis­(methane­sulfonato-κo)(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) n,n′,n′′,n′′′)tin(iv) chloro­form tris­olvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344358/
https://www.ncbi.nlm.nih.gov/pubmed/22590124
http://dx.doi.org/10.1107/S1600536812015875
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