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catena-Poly[[[aqua­(pyrazine-2-carboxamide-κ(2) N (1),O)zinc]-μ-pyrazine-2-carboxamide-κ(3) N (1),O:N (4)] dinitrate]

In the crystal of the title compound, {[Zn(C(5)H(5)N(3)O)(2)(H(2)O)](NO(3))(2)}(n), the Zn(II) cation is N,O-chelated by two pyrazine-2-carboxamide (PCA) ligands and is further coordinated by one water mol­ecule and by one pyrazine-N atom from an adjacent PCA ligand in a distorted ZnN(3)O(3) octa­he...

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Detalles Bibliográficos
Autores principales: Shirvan, Sadif A., Haydari Dezfuli, Sara
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344359/
https://www.ncbi.nlm.nih.gov/pubmed/22590125
http://dx.doi.org/10.1107/S1600536812016017
Descripción
Sumario:In the crystal of the title compound, {[Zn(C(5)H(5)N(3)O)(2)(H(2)O)](NO(3))(2)}(n), the Zn(II) cation is N,O-chelated by two pyrazine-2-carboxamide (PCA) ligands and is further coordinated by one water mol­ecule and by one pyrazine-N atom from an adjacent PCA ligand in a distorted ZnN(3)O(3) octa­hedral geometry. One of the two independent PCA ligands bridges two Zn(II) cations, forming a zigzag polymeric chain running along the c axis. In the crystal, the NO(3) (−) anions link to the chain via O—H⋯O and N—H⋯O hydrogen bonding. Weak inter­molecular C—H⋯O inter­actions also occur.