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catena-Poly[[[aqua(pyrazine-2-carboxamide-κ(2) N (1),O)zinc]-μ-pyrazine-2-carboxamide-κ(3) N (1),O:N (4)] dinitrate]
In the crystal of the title compound, {[Zn(C(5)H(5)N(3)O)(2)(H(2)O)](NO(3))(2)}(n), the Zn(II) cation is N,O-chelated by two pyrazine-2-carboxamide (PCA) ligands and is further coordinated by one water molecule and by one pyrazine-N atom from an adjacent PCA ligand in a distorted ZnN(3)O(3) octahe...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344359/ https://www.ncbi.nlm.nih.gov/pubmed/22590125 http://dx.doi.org/10.1107/S1600536812016017 |
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author | Shirvan, Sadif A. Haydari Dezfuli, Sara |
author_facet | Shirvan, Sadif A. Haydari Dezfuli, Sara |
author_sort | Shirvan, Sadif A. |
collection | PubMed |
description | In the crystal of the title compound, {[Zn(C(5)H(5)N(3)O)(2)(H(2)O)](NO(3))(2)}(n), the Zn(II) cation is N,O-chelated by two pyrazine-2-carboxamide (PCA) ligands and is further coordinated by one water molecule and by one pyrazine-N atom from an adjacent PCA ligand in a distorted ZnN(3)O(3) octahedral geometry. One of the two independent PCA ligands bridges two Zn(II) cations, forming a zigzag polymeric chain running along the c axis. In the crystal, the NO(3) (−) anions link to the chain via O—H⋯O and N—H⋯O hydrogen bonding. Weak intermolecular C—H⋯O interactions also occur. |
format | Online Article Text |
id | pubmed-3344359 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33443592012-05-15 catena-Poly[[[aqua(pyrazine-2-carboxamide-κ(2) N (1),O)zinc]-μ-pyrazine-2-carboxamide-κ(3) N (1),O:N (4)] dinitrate] Shirvan, Sadif A. Haydari Dezfuli, Sara Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal of the title compound, {[Zn(C(5)H(5)N(3)O)(2)(H(2)O)](NO(3))(2)}(n), the Zn(II) cation is N,O-chelated by two pyrazine-2-carboxamide (PCA) ligands and is further coordinated by one water molecule and by one pyrazine-N atom from an adjacent PCA ligand in a distorted ZnN(3)O(3) octahedral geometry. One of the two independent PCA ligands bridges two Zn(II) cations, forming a zigzag polymeric chain running along the c axis. In the crystal, the NO(3) (−) anions link to the chain via O—H⋯O and N—H⋯O hydrogen bonding. Weak intermolecular C—H⋯O interactions also occur. International Union of Crystallography 2012-04-18 /pmc/articles/PMC3344359/ /pubmed/22590125 http://dx.doi.org/10.1107/S1600536812016017 Text en © Shirvan and Haydari Dezfuli 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Shirvan, Sadif A. Haydari Dezfuli, Sara catena-Poly[[[aqua(pyrazine-2-carboxamide-κ(2) N (1),O)zinc]-μ-pyrazine-2-carboxamide-κ(3) N (1),O:N (4)] dinitrate] |
title |
catena-Poly[[[aqua(pyrazine-2-carboxamide-κ(2)
N
(1),O)zinc]-μ-pyrazine-2-carboxamide-κ(3)
N
(1),O:N
(4)] dinitrate] |
title_full |
catena-Poly[[[aqua(pyrazine-2-carboxamide-κ(2)
N
(1),O)zinc]-μ-pyrazine-2-carboxamide-κ(3)
N
(1),O:N
(4)] dinitrate] |
title_fullStr |
catena-Poly[[[aqua(pyrazine-2-carboxamide-κ(2)
N
(1),O)zinc]-μ-pyrazine-2-carboxamide-κ(3)
N
(1),O:N
(4)] dinitrate] |
title_full_unstemmed |
catena-Poly[[[aqua(pyrazine-2-carboxamide-κ(2)
N
(1),O)zinc]-μ-pyrazine-2-carboxamide-κ(3)
N
(1),O:N
(4)] dinitrate] |
title_short |
catena-Poly[[[aqua(pyrazine-2-carboxamide-κ(2)
N
(1),O)zinc]-μ-pyrazine-2-carboxamide-κ(3)
N
(1),O:N
(4)] dinitrate] |
title_sort | catena-poly[[[aqua(pyrazine-2-carboxamide-κ(2)
n
(1),o)zinc]-μ-pyrazine-2-carboxamide-κ(3)
n
(1),o:n
(4)] dinitrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344359/ https://www.ncbi.nlm.nih.gov/pubmed/22590125 http://dx.doi.org/10.1107/S1600536812016017 |
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