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catena-Poly[[[aqua­(pyrazine-2-carboxamide-κ(2) N (1),O)zinc]-μ-pyrazine-2-carboxamide-κ(3) N (1),O:N (4)] dinitrate]

In the crystal of the title compound, {[Zn(C(5)H(5)N(3)O)(2)(H(2)O)](NO(3))(2)}(n), the Zn(II) cation is N,O-chelated by two pyrazine-2-carboxamide (PCA) ligands and is further coordinated by one water mol­ecule and by one pyrazine-N atom from an adjacent PCA ligand in a distorted ZnN(3)O(3) octa­he...

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Detalles Bibliográficos
Autores principales: Shirvan, Sadif A., Haydari Dezfuli, Sara
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344359/
https://www.ncbi.nlm.nih.gov/pubmed/22590125
http://dx.doi.org/10.1107/S1600536812016017
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author Shirvan, Sadif A.
Haydari Dezfuli, Sara
author_facet Shirvan, Sadif A.
Haydari Dezfuli, Sara
author_sort Shirvan, Sadif A.
collection PubMed
description In the crystal of the title compound, {[Zn(C(5)H(5)N(3)O)(2)(H(2)O)](NO(3))(2)}(n), the Zn(II) cation is N,O-chelated by two pyrazine-2-carboxamide (PCA) ligands and is further coordinated by one water mol­ecule and by one pyrazine-N atom from an adjacent PCA ligand in a distorted ZnN(3)O(3) octa­hedral geometry. One of the two independent PCA ligands bridges two Zn(II) cations, forming a zigzag polymeric chain running along the c axis. In the crystal, the NO(3) (−) anions link to the chain via O—H⋯O and N—H⋯O hydrogen bonding. Weak inter­molecular C—H⋯O inter­actions also occur.
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spelling pubmed-33443592012-05-15 catena-Poly[[[aqua­(pyrazine-2-carboxamide-κ(2) N (1),O)zinc]-μ-pyrazine-2-carboxamide-κ(3) N (1),O:N (4)] dinitrate] Shirvan, Sadif A. Haydari Dezfuli, Sara Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal of the title compound, {[Zn(C(5)H(5)N(3)O)(2)(H(2)O)](NO(3))(2)}(n), the Zn(II) cation is N,O-chelated by two pyrazine-2-carboxamide (PCA) ligands and is further coordinated by one water mol­ecule and by one pyrazine-N atom from an adjacent PCA ligand in a distorted ZnN(3)O(3) octa­hedral geometry. One of the two independent PCA ligands bridges two Zn(II) cations, forming a zigzag polymeric chain running along the c axis. In the crystal, the NO(3) (−) anions link to the chain via O—H⋯O and N—H⋯O hydrogen bonding. Weak inter­molecular C—H⋯O inter­actions also occur. International Union of Crystallography 2012-04-18 /pmc/articles/PMC3344359/ /pubmed/22590125 http://dx.doi.org/10.1107/S1600536812016017 Text en © Shirvan and Haydari Dezfuli 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shirvan, Sadif A.
Haydari Dezfuli, Sara
catena-Poly[[[aqua­(pyrazine-2-carboxamide-κ(2) N (1),O)zinc]-μ-pyrazine-2-carboxamide-κ(3) N (1),O:N (4)] dinitrate]
title catena-Poly[[[aqua­(pyrazine-2-carboxamide-κ(2) N (1),O)zinc]-μ-pyrazine-2-carboxamide-κ(3) N (1),O:N (4)] dinitrate]
title_full catena-Poly[[[aqua­(pyrazine-2-carboxamide-κ(2) N (1),O)zinc]-μ-pyrazine-2-carboxamide-κ(3) N (1),O:N (4)] dinitrate]
title_fullStr catena-Poly[[[aqua­(pyrazine-2-carboxamide-κ(2) N (1),O)zinc]-μ-pyrazine-2-carboxamide-κ(3) N (1),O:N (4)] dinitrate]
title_full_unstemmed catena-Poly[[[aqua­(pyrazine-2-carboxamide-κ(2) N (1),O)zinc]-μ-pyrazine-2-carboxamide-κ(3) N (1),O:N (4)] dinitrate]
title_short catena-Poly[[[aqua­(pyrazine-2-carboxamide-κ(2) N (1),O)zinc]-μ-pyrazine-2-carboxamide-κ(3) N (1),O:N (4)] dinitrate]
title_sort catena-poly[[[aqua­(pyrazine-2-carboxamide-κ(2) n (1),o)zinc]-μ-pyrazine-2-carboxamide-κ(3) n (1),o:n (4)] dinitrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344359/
https://www.ncbi.nlm.nih.gov/pubmed/22590125
http://dx.doi.org/10.1107/S1600536812016017
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