Cargando…
Bis(3,5-dimethyl-1H-pyrazole-κN (2))bis(3,3′′,5,5′′-tetramethyl-[1,1′:3′,1′′-terphenyl]-2′-carboxylato-κO)iron(II) dichloromethane monosolvate
In the title compound, [Fe(C(23)H(21)O(2))(2)(C(5)H(8)N(2))(2)]·CH(2)Cl(2), the Fe(2+) cation is coordinated by the N atoms of two 3,5-dimethylpyrazole ligands and the carboxylate O atoms from two tetramethylterphenylcarboxylate ligands, forming an FeN(2)O(2) polyhedron with a slightly distort...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344361/ https://www.ncbi.nlm.nih.gov/pubmed/22590127 http://dx.doi.org/10.1107/S1600536812015553 |
_version_ | 1782231975244857344 |
---|---|
author | Jeon, Yeojin Sivanesan, Dharmalingam Yoon, Sungho |
author_facet | Jeon, Yeojin Sivanesan, Dharmalingam Yoon, Sungho |
author_sort | Jeon, Yeojin |
collection | PubMed |
description | In the title compound, [Fe(C(23)H(21)O(2))(2)(C(5)H(8)N(2))(2)]·CH(2)Cl(2), the Fe(2+) cation is coordinated by the N atoms of two 3,5-dimethylpyrazole ligands and the carboxylate O atoms from two tetramethylterphenylcarboxylate ligands, forming an FeN(2)O(2) polyhedron with a slightly distorted tetrahedral coordination geometry. Intramolecular N—H⋯O and C—H⋯O hydrogen-bonding interactions stabilize the molecular conformation. The dihedral angles formed by the central benzene ring with the outer benzene rings of the terphenyl groups are 47.92 (8), 59.38 (8), 48.24 (8) and 52.37 (8)°. The dichloromethane solvent molecule interacts with the complex molecule via a C—H⋯O hydrogen bond. In the crystal, centrosymmetrically related complex molecules are linked into dimers through pairs of C—H⋯O hydrogen bonds. |
format | Online Article Text |
id | pubmed-3344361 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33443612012-05-15 Bis(3,5-dimethyl-1H-pyrazole-κN (2))bis(3,3′′,5,5′′-tetramethyl-[1,1′:3′,1′′-terphenyl]-2′-carboxylato-κO)iron(II) dichloromethane monosolvate Jeon, Yeojin Sivanesan, Dharmalingam Yoon, Sungho Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(C(23)H(21)O(2))(2)(C(5)H(8)N(2))(2)]·CH(2)Cl(2), the Fe(2+) cation is coordinated by the N atoms of two 3,5-dimethylpyrazole ligands and the carboxylate O atoms from two tetramethylterphenylcarboxylate ligands, forming an FeN(2)O(2) polyhedron with a slightly distorted tetrahedral coordination geometry. Intramolecular N—H⋯O and C—H⋯O hydrogen-bonding interactions stabilize the molecular conformation. The dihedral angles formed by the central benzene ring with the outer benzene rings of the terphenyl groups are 47.92 (8), 59.38 (8), 48.24 (8) and 52.37 (8)°. The dichloromethane solvent molecule interacts with the complex molecule via a C—H⋯O hydrogen bond. In the crystal, centrosymmetrically related complex molecules are linked into dimers through pairs of C—H⋯O hydrogen bonds. International Union of Crystallography 2012-04-18 /pmc/articles/PMC3344361/ /pubmed/22590127 http://dx.doi.org/10.1107/S1600536812015553 Text en © Jeon et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Jeon, Yeojin Sivanesan, Dharmalingam Yoon, Sungho Bis(3,5-dimethyl-1H-pyrazole-κN (2))bis(3,3′′,5,5′′-tetramethyl-[1,1′:3′,1′′-terphenyl]-2′-carboxylato-κO)iron(II) dichloromethane monosolvate |
title | Bis(3,5-dimethyl-1H-pyrazole-κN
(2))bis(3,3′′,5,5′′-tetramethyl-[1,1′:3′,1′′-terphenyl]-2′-carboxylato-κO)iron(II) dichloromethane monosolvate |
title_full | Bis(3,5-dimethyl-1H-pyrazole-κN
(2))bis(3,3′′,5,5′′-tetramethyl-[1,1′:3′,1′′-terphenyl]-2′-carboxylato-κO)iron(II) dichloromethane monosolvate |
title_fullStr | Bis(3,5-dimethyl-1H-pyrazole-κN
(2))bis(3,3′′,5,5′′-tetramethyl-[1,1′:3′,1′′-terphenyl]-2′-carboxylato-κO)iron(II) dichloromethane monosolvate |
title_full_unstemmed | Bis(3,5-dimethyl-1H-pyrazole-κN
(2))bis(3,3′′,5,5′′-tetramethyl-[1,1′:3′,1′′-terphenyl]-2′-carboxylato-κO)iron(II) dichloromethane monosolvate |
title_short | Bis(3,5-dimethyl-1H-pyrazole-κN
(2))bis(3,3′′,5,5′′-tetramethyl-[1,1′:3′,1′′-terphenyl]-2′-carboxylato-κO)iron(II) dichloromethane monosolvate |
title_sort | bis(3,5-dimethyl-1h-pyrazole-κn
(2))bis(3,3′′,5,5′′-tetramethyl-[1,1′:3′,1′′-terphenyl]-2′-carboxylato-κo)iron(ii) dichloromethane monosolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344361/ https://www.ncbi.nlm.nih.gov/pubmed/22590127 http://dx.doi.org/10.1107/S1600536812015553 |
work_keys_str_mv | AT jeonyeojin bis35dimethyl1hpyrazolekn2bis3355tetramethyl1131terphenyl2carboxylatokoironiidichloromethanemonosolvate AT sivanesandharmalingam bis35dimethyl1hpyrazolekn2bis3355tetramethyl1131terphenyl2carboxylatokoironiidichloromethanemonosolvate AT yoonsungho bis35dimethyl1hpyrazolekn2bis3355tetramethyl1131terphenyl2carboxylatokoironiidichloromethanemonosolvate |