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Bis(3,5-dimethyl-1H-pyrazole-κN (2))bis­(3,3′′,5,5′′-tetra­methyl-[1,1′:3′,1′′-terphen­yl]-2′-carboxyl­ato-κO)iron(II) dichloro­methane monosolvate

In the title compound, [Fe(C(23)H(21)O(2))(2)(C(5)H(8)N(2))(2)]·CH(2)Cl(2), the Fe(2+) cation is coordinated by the N atoms of two 3,5-dimethyl­pyrazole ligands and the carboxyl­ate O atoms from two tetra­methyl­terphenyl­carboxyl­ate ligands, forming an FeN(2)O(2) polyhedron with a slightly distort...

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Detalles Bibliográficos
Autores principales: Jeon, Yeojin, Sivanesan, Dharmalingam, Yoon, Sungho
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344361/
https://www.ncbi.nlm.nih.gov/pubmed/22590127
http://dx.doi.org/10.1107/S1600536812015553
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author Jeon, Yeojin
Sivanesan, Dharmalingam
Yoon, Sungho
author_facet Jeon, Yeojin
Sivanesan, Dharmalingam
Yoon, Sungho
author_sort Jeon, Yeojin
collection PubMed
description In the title compound, [Fe(C(23)H(21)O(2))(2)(C(5)H(8)N(2))(2)]·CH(2)Cl(2), the Fe(2+) cation is coordinated by the N atoms of two 3,5-dimethyl­pyrazole ligands and the carboxyl­ate O atoms from two tetra­methyl­terphenyl­carboxyl­ate ligands, forming an FeN(2)O(2) polyhedron with a slightly distorted tetra­hedral coordination geometry. Intra­molecular N—H⋯O and C—H⋯O hydrogen-bonding inter­actions stabilize the mol­ecular conformation. The dihedral angles formed by the central benzene ring with the outer benzene rings of the terphenyl groups are 47.92 (8), 59.38 (8), 48.24 (8) and 52.37 (8)°. The dichloro­methane solvent mol­ecule inter­acts with the complex mol­ecule via a C—H⋯O hydrogen bond. In the crystal, centrosymmetrically related complex mol­ecules are linked into dimers through pairs of C—H⋯O hydrogen bonds.
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spelling pubmed-33443612012-05-15 Bis(3,5-dimethyl-1H-pyrazole-κN (2))bis­(3,3′′,5,5′′-tetra­methyl-[1,1′:3′,1′′-terphen­yl]-2′-carboxyl­ato-κO)iron(II) dichloro­methane monosolvate Jeon, Yeojin Sivanesan, Dharmalingam Yoon, Sungho Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(C(23)H(21)O(2))(2)(C(5)H(8)N(2))(2)]·CH(2)Cl(2), the Fe(2+) cation is coordinated by the N atoms of two 3,5-dimethyl­pyrazole ligands and the carboxyl­ate O atoms from two tetra­methyl­terphenyl­carboxyl­ate ligands, forming an FeN(2)O(2) polyhedron with a slightly distorted tetra­hedral coordination geometry. Intra­molecular N—H⋯O and C—H⋯O hydrogen-bonding inter­actions stabilize the mol­ecular conformation. The dihedral angles formed by the central benzene ring with the outer benzene rings of the terphenyl groups are 47.92 (8), 59.38 (8), 48.24 (8) and 52.37 (8)°. The dichloro­methane solvent mol­ecule inter­acts with the complex mol­ecule via a C—H⋯O hydrogen bond. In the crystal, centrosymmetrically related complex mol­ecules are linked into dimers through pairs of C—H⋯O hydrogen bonds. International Union of Crystallography 2012-04-18 /pmc/articles/PMC3344361/ /pubmed/22590127 http://dx.doi.org/10.1107/S1600536812015553 Text en © Jeon et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jeon, Yeojin
Sivanesan, Dharmalingam
Yoon, Sungho
Bis(3,5-dimethyl-1H-pyrazole-κN (2))bis­(3,3′′,5,5′′-tetra­methyl-[1,1′:3′,1′′-terphen­yl]-2′-carboxyl­ato-κO)iron(II) dichloro­methane monosolvate
title Bis(3,5-dimethyl-1H-pyrazole-κN (2))bis­(3,3′′,5,5′′-tetra­methyl-[1,1′:3′,1′′-terphen­yl]-2′-carboxyl­ato-κO)iron(II) dichloro­methane monosolvate
title_full Bis(3,5-dimethyl-1H-pyrazole-κN (2))bis­(3,3′′,5,5′′-tetra­methyl-[1,1′:3′,1′′-terphen­yl]-2′-carboxyl­ato-κO)iron(II) dichloro­methane monosolvate
title_fullStr Bis(3,5-dimethyl-1H-pyrazole-κN (2))bis­(3,3′′,5,5′′-tetra­methyl-[1,1′:3′,1′′-terphen­yl]-2′-carboxyl­ato-κO)iron(II) dichloro­methane monosolvate
title_full_unstemmed Bis(3,5-dimethyl-1H-pyrazole-κN (2))bis­(3,3′′,5,5′′-tetra­methyl-[1,1′:3′,1′′-terphen­yl]-2′-carboxyl­ato-κO)iron(II) dichloro­methane monosolvate
title_short Bis(3,5-dimethyl-1H-pyrazole-κN (2))bis­(3,3′′,5,5′′-tetra­methyl-[1,1′:3′,1′′-terphen­yl]-2′-carboxyl­ato-κO)iron(II) dichloro­methane monosolvate
title_sort bis(3,5-dimethyl-1h-pyrazole-κn (2))bis­(3,3′′,5,5′′-tetra­methyl-[1,1′:3′,1′′-terphen­yl]-2′-carboxyl­ato-κo)iron(ii) dichloro­methane monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344361/
https://www.ncbi.nlm.nih.gov/pubmed/22590127
http://dx.doi.org/10.1107/S1600536812015553
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