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Poly[[tris­(μ-4,4′-bipyridine-κ(2) N:N′)bis­(μ-l-lysinato-κ(3) N (1),O (1):O (1′))dizinc(II)] tetra­nitrate 0.6-hydrate dimethyl­formamide disolvate]

In the title compound, {[Zn(2)(C(6)H(14)N(2)O(2))(2)(C(10)H(8)N(2))(3)](NO(3))(4)·0.6H(2)O·2C(3)H(7)NO}(n), the Zn(II) ion is six-coordinated with a distorted octa­hedral geometry by two carboxyl­ate O atoms and one amino N atom from two l-lysinate (l-lys) ligands, and three N atoms from three 4,4′-...

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Detalles Bibliográficos
Autores principales: Li, Shu-Qiang, Hu, Ning-Hai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344362/
https://www.ncbi.nlm.nih.gov/pubmed/22590128
http://dx.doi.org/10.1107/S1600536812016121
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author Li, Shu-Qiang
Hu, Ning-Hai
author_facet Li, Shu-Qiang
Hu, Ning-Hai
author_sort Li, Shu-Qiang
collection PubMed
description In the title compound, {[Zn(2)(C(6)H(14)N(2)O(2))(2)(C(10)H(8)N(2))(3)](NO(3))(4)·0.6H(2)O·2C(3)H(7)NO}(n), the Zn(II) ion is six-coordinated with a distorted octa­hedral geometry by two carboxyl­ate O atoms and one amino N atom from two l-lysinate (l-lys) ligands, and three N atoms from three 4,4′-bipyridine (4,4′-bipy) ligands. The Zn(II) ions are connected by the carboxyl­ate groups of the l-lys ligands in the a-axis direction and the bridging 4,4′-bipy ligands in the b- and c-axis directions, forming a three-dimensional cationic framework with channels along [100]. The nitrate anions and solvent water and dimethyl­formamide (DMF) mol­ecules are located in the channels and linked to the cationic framework by N—H⋯O and O—H⋯O hydrogen bonds. The occupancy of the water mol­ecule was fixed at 0.6. One of the DMF mol­ecules is disordered over two sets of sites, with an occupancy ratio of 0.632:0.368 (11).
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spelling pubmed-33443622012-05-15 Poly[[tris­(μ-4,4′-bipyridine-κ(2) N:N′)bis­(μ-l-lysinato-κ(3) N (1),O (1):O (1′))dizinc(II)] tetra­nitrate 0.6-hydrate dimethyl­formamide disolvate] Li, Shu-Qiang Hu, Ning-Hai Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Zn(2)(C(6)H(14)N(2)O(2))(2)(C(10)H(8)N(2))(3)](NO(3))(4)·0.6H(2)O·2C(3)H(7)NO}(n), the Zn(II) ion is six-coordinated with a distorted octa­hedral geometry by two carboxyl­ate O atoms and one amino N atom from two l-lysinate (l-lys) ligands, and three N atoms from three 4,4′-bipyridine (4,4′-bipy) ligands. The Zn(II) ions are connected by the carboxyl­ate groups of the l-lys ligands in the a-axis direction and the bridging 4,4′-bipy ligands in the b- and c-axis directions, forming a three-dimensional cationic framework with channels along [100]. The nitrate anions and solvent water and dimethyl­formamide (DMF) mol­ecules are located in the channels and linked to the cationic framework by N—H⋯O and O—H⋯O hydrogen bonds. The occupancy of the water mol­ecule was fixed at 0.6. One of the DMF mol­ecules is disordered over two sets of sites, with an occupancy ratio of 0.632:0.368 (11). International Union of Crystallography 2012-04-21 /pmc/articles/PMC3344362/ /pubmed/22590128 http://dx.doi.org/10.1107/S1600536812016121 Text en © Li and Hu 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Shu-Qiang
Hu, Ning-Hai
Poly[[tris­(μ-4,4′-bipyridine-κ(2) N:N′)bis­(μ-l-lysinato-κ(3) N (1),O (1):O (1′))dizinc(II)] tetra­nitrate 0.6-hydrate dimethyl­formamide disolvate]
title Poly[[tris­(μ-4,4′-bipyridine-κ(2) N:N′)bis­(μ-l-lysinato-κ(3) N (1),O (1):O (1′))dizinc(II)] tetra­nitrate 0.6-hydrate dimethyl­formamide disolvate]
title_full Poly[[tris­(μ-4,4′-bipyridine-κ(2) N:N′)bis­(μ-l-lysinato-κ(3) N (1),O (1):O (1′))dizinc(II)] tetra­nitrate 0.6-hydrate dimethyl­formamide disolvate]
title_fullStr Poly[[tris­(μ-4,4′-bipyridine-κ(2) N:N′)bis­(μ-l-lysinato-κ(3) N (1),O (1):O (1′))dizinc(II)] tetra­nitrate 0.6-hydrate dimethyl­formamide disolvate]
title_full_unstemmed Poly[[tris­(μ-4,4′-bipyridine-κ(2) N:N′)bis­(μ-l-lysinato-κ(3) N (1),O (1):O (1′))dizinc(II)] tetra­nitrate 0.6-hydrate dimethyl­formamide disolvate]
title_short Poly[[tris­(μ-4,4′-bipyridine-κ(2) N:N′)bis­(μ-l-lysinato-κ(3) N (1),O (1):O (1′))dizinc(II)] tetra­nitrate 0.6-hydrate dimethyl­formamide disolvate]
title_sort poly[[tris­(μ-4,4′-bipyridine-κ(2) n:n′)bis­(μ-l-lysinato-κ(3) n (1),o (1):o (1′))dizinc(ii)] tetra­nitrate 0.6-hydrate dimethyl­formamide disolvate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344362/
https://www.ncbi.nlm.nih.gov/pubmed/22590128
http://dx.doi.org/10.1107/S1600536812016121
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