Bis{4-phenyl-1-[1-(pyridin-2-yl-κN)ethyl­idene]thio­semicarbazidato-κ(2) N (1),S}cadmium

The reaction of cadmium acetate dihydrate with 2-acetyl­pyridine (4-phenyl­thio­semicarbazone) yielded the title compound, [Cd(C(14)H(13)N(4)S)(2)]. The Cd(II) atom is six-coordin­ated in a distorted octa­hedral environment by two deproton­ated thio­semicarbazone ligands acting in a tridentate chela...

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Autores principales: Fonseca, Alexandra de Souza, Gervini, Vanessa Carratu, Bresolin, Leandro, Locatelli, Aline, de Oliveira, Adriano Bof
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344363/
https://www.ncbi.nlm.nih.gov/pubmed/22590129
http://dx.doi.org/10.1107/S1600536812016558
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author Fonseca, Alexandra de Souza
Gervini, Vanessa Carratu
Bresolin, Leandro
Locatelli, Aline
de Oliveira, Adriano Bof
author_facet Fonseca, Alexandra de Souza
Gervini, Vanessa Carratu
Bresolin, Leandro
Locatelli, Aline
de Oliveira, Adriano Bof
author_sort Fonseca, Alexandra de Souza
collection PubMed
description The reaction of cadmium acetate dihydrate with 2-acetyl­pyridine (4-phenyl­thio­semicarbazone) yielded the title compound, [Cd(C(14)H(13)N(4)S)(2)]. The Cd(II) atom is six-coordin­ated in a distorted octa­hedral environment by two deproton­ated thio­semicarbazone ligands acting in a tridentate chelating mode through two N and one S atoms, forming metalla-rings. In the crystal, mol­ecules are connected through inversion centers via pairs of N—H⋯S inter­actions, building a one-dimensional hydrogen-bonded polymer along [0-1-1].
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spelling pubmed-33443632012-05-15 Bis{4-phenyl-1-[1-(pyridin-2-yl-κN)ethyl­idene]thio­semicarbazidato-κ(2) N (1),S}cadmium Fonseca, Alexandra de Souza Gervini, Vanessa Carratu Bresolin, Leandro Locatelli, Aline de Oliveira, Adriano Bof Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of cadmium acetate dihydrate with 2-acetyl­pyridine (4-phenyl­thio­semicarbazone) yielded the title compound, [Cd(C(14)H(13)N(4)S)(2)]. The Cd(II) atom is six-coordin­ated in a distorted octa­hedral environment by two deproton­ated thio­semicarbazone ligands acting in a tridentate chelating mode through two N and one S atoms, forming metalla-rings. In the crystal, mol­ecules are connected through inversion centers via pairs of N—H⋯S inter­actions, building a one-dimensional hydrogen-bonded polymer along [0-1-1]. International Union of Crystallography 2012-04-21 /pmc/articles/PMC3344363/ /pubmed/22590129 http://dx.doi.org/10.1107/S1600536812016558 Text en © Fonseca et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fonseca, Alexandra de Souza
Gervini, Vanessa Carratu
Bresolin, Leandro
Locatelli, Aline
de Oliveira, Adriano Bof
Bis{4-phenyl-1-[1-(pyridin-2-yl-κN)ethyl­idene]thio­semicarbazidato-κ(2) N (1),S}cadmium
title Bis{4-phenyl-1-[1-(pyridin-2-yl-κN)ethyl­idene]thio­semicarbazidato-κ(2) N (1),S}cadmium
title_full Bis{4-phenyl-1-[1-(pyridin-2-yl-κN)ethyl­idene]thio­semicarbazidato-κ(2) N (1),S}cadmium
title_fullStr Bis{4-phenyl-1-[1-(pyridin-2-yl-κN)ethyl­idene]thio­semicarbazidato-κ(2) N (1),S}cadmium
title_full_unstemmed Bis{4-phenyl-1-[1-(pyridin-2-yl-κN)ethyl­idene]thio­semicarbazidato-κ(2) N (1),S}cadmium
title_short Bis{4-phenyl-1-[1-(pyridin-2-yl-κN)ethyl­idene]thio­semicarbazidato-κ(2) N (1),S}cadmium
title_sort bis{4-phenyl-1-[1-(pyridin-2-yl-κn)ethyl­idene]thio­semicarbazidato-κ(2) n (1),s}cadmium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344363/
https://www.ncbi.nlm.nih.gov/pubmed/22590129
http://dx.doi.org/10.1107/S1600536812016558
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