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catena-Poly[[silver(I)-μ-1,2-bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane-κ(2) N:N′] perchlorate hemihydrate]
In the title coordination polymer, {[Ag(C(12)H(20)N(2)O(2))]ClO(4)·0.5H(2)O}(n), the Ag(I) cation is coordinated by two N atoms from two 1,2-bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane (L) ligands in a nearly linear geometry [N—Ag—N = 171.07 (8)°]. The L ligand bridges adjacent Ag(+) cation...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344364/ https://www.ncbi.nlm.nih.gov/pubmed/22590130 http://dx.doi.org/10.1107/S1600536812016406 |
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author | Yeh, Chun-Wei Huang, Fu-Chang Lin, Shui-Chuan Jong, Ay Suen, Maw-Cherng |
author_facet | Yeh, Chun-Wei Huang, Fu-Chang Lin, Shui-Chuan Jong, Ay Suen, Maw-Cherng |
author_sort | Yeh, Chun-Wei |
collection | PubMed |
description | In the title coordination polymer, {[Ag(C(12)H(20)N(2)O(2))]ClO(4)·0.5H(2)O}(n), the Ag(I) cation is coordinated by two N atoms from two 1,2-bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane (L) ligands in a nearly linear geometry [N—Ag—N = 171.07 (8)°]. The L ligand bridges adjacent Ag(+) cations, forming a polymeric chain running along the c axis. The lattice water molecule is situated on a twofold rotation axis, and links to the perchlorate anion via an O—H⋯O hydrogen bond. The long Ag⋯O separation of 3.200 (4) Å indicates a weak interaction between the perchlorate anion and the Ag(I) cation. Weak C—H⋯O hydrogen bonding occurs between the chain and the lattice water molecule and between the chain and perchlorate anions. Both five-membered rings of the L ligand display envelope conformations; in one five-membered ring, the flap C atom is disordered on opposite sides of the ring with occupancies of 0.65 and 0.35. |
format | Online Article Text |
id | pubmed-3344364 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33443642012-05-15 catena-Poly[[silver(I)-μ-1,2-bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane-κ(2) N:N′] perchlorate hemihydrate] Yeh, Chun-Wei Huang, Fu-Chang Lin, Shui-Chuan Jong, Ay Suen, Maw-Cherng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, {[Ag(C(12)H(20)N(2)O(2))]ClO(4)·0.5H(2)O}(n), the Ag(I) cation is coordinated by two N atoms from two 1,2-bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane (L) ligands in a nearly linear geometry [N—Ag—N = 171.07 (8)°]. The L ligand bridges adjacent Ag(+) cations, forming a polymeric chain running along the c axis. The lattice water molecule is situated on a twofold rotation axis, and links to the perchlorate anion via an O—H⋯O hydrogen bond. The long Ag⋯O separation of 3.200 (4) Å indicates a weak interaction between the perchlorate anion and the Ag(I) cation. Weak C—H⋯O hydrogen bonding occurs between the chain and the lattice water molecule and between the chain and perchlorate anions. Both five-membered rings of the L ligand display envelope conformations; in one five-membered ring, the flap C atom is disordered on opposite sides of the ring with occupancies of 0.65 and 0.35. International Union of Crystallography 2012-04-21 /pmc/articles/PMC3344364/ /pubmed/22590130 http://dx.doi.org/10.1107/S1600536812016406 Text en © Yeh et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yeh, Chun-Wei Huang, Fu-Chang Lin, Shui-Chuan Jong, Ay Suen, Maw-Cherng catena-Poly[[silver(I)-μ-1,2-bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane-κ(2) N:N′] perchlorate hemihydrate] |
title |
catena-Poly[[silver(I)-μ-1,2-bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane-κ(2)
N:N′] perchlorate hemihydrate] |
title_full |
catena-Poly[[silver(I)-μ-1,2-bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane-κ(2)
N:N′] perchlorate hemihydrate] |
title_fullStr |
catena-Poly[[silver(I)-μ-1,2-bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane-κ(2)
N:N′] perchlorate hemihydrate] |
title_full_unstemmed |
catena-Poly[[silver(I)-μ-1,2-bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane-κ(2)
N:N′] perchlorate hemihydrate] |
title_short |
catena-Poly[[silver(I)-μ-1,2-bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane-κ(2)
N:N′] perchlorate hemihydrate] |
title_sort | catena-poly[[silver(i)-μ-1,2-bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane-κ(2)
n:n′] perchlorate hemihydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344364/ https://www.ncbi.nlm.nih.gov/pubmed/22590130 http://dx.doi.org/10.1107/S1600536812016406 |
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