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catena-Poly[[silver(I)-μ-1,2-bis­(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane-κ(2) N:N′] perchlorate hemihydrate]

In the title coordination polymer, {[Ag(C(12)H(20)N(2)O(2))]ClO(4)·0.5H(2)O}(n), the Ag(I) cation is coordinated by two N atoms from two 1,2-bis­(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane (L) ligands in a nearly linear geometry [N—Ag—N = 171.07 (8)°]. The L ligand bridges adjacent Ag(+) cation...

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Detalles Bibliográficos
Autores principales: Yeh, Chun-Wei, Huang, Fu-Chang, Lin, Shui-Chuan, Jong, Ay, Suen, Maw-Cherng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344364/
https://www.ncbi.nlm.nih.gov/pubmed/22590130
http://dx.doi.org/10.1107/S1600536812016406
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author Yeh, Chun-Wei
Huang, Fu-Chang
Lin, Shui-Chuan
Jong, Ay
Suen, Maw-Cherng
author_facet Yeh, Chun-Wei
Huang, Fu-Chang
Lin, Shui-Chuan
Jong, Ay
Suen, Maw-Cherng
author_sort Yeh, Chun-Wei
collection PubMed
description In the title coordination polymer, {[Ag(C(12)H(20)N(2)O(2))]ClO(4)·0.5H(2)O}(n), the Ag(I) cation is coordinated by two N atoms from two 1,2-bis­(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane (L) ligands in a nearly linear geometry [N—Ag—N = 171.07 (8)°]. The L ligand bridges adjacent Ag(+) cations, forming a polymeric chain running along the c axis. The lattice water mol­ecule is situated on a twofold rotation axis, and links to the perchlorate anion via an O—H⋯O hydrogen bond. The long Ag⋯O separation of 3.200 (4) Å indicates a weak inter­action between the perchlorate anion and the Ag(I) cation. Weak C—H⋯O hydrogen bonding occurs between the chain and the lattice water mol­ecule and between the chain and perchlorate anions. Both five-membered rings of the L ligand display envelope conformations; in one five-membered ring, the flap C atom is disordered on opposite sides of the ring with occupancies of 0.65 and 0.35.
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spelling pubmed-33443642012-05-15 catena-Poly[[silver(I)-μ-1,2-bis­(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane-κ(2) N:N′] perchlorate hemihydrate] Yeh, Chun-Wei Huang, Fu-Chang Lin, Shui-Chuan Jong, Ay Suen, Maw-Cherng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, {[Ag(C(12)H(20)N(2)O(2))]ClO(4)·0.5H(2)O}(n), the Ag(I) cation is coordinated by two N atoms from two 1,2-bis­(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane (L) ligands in a nearly linear geometry [N—Ag—N = 171.07 (8)°]. The L ligand bridges adjacent Ag(+) cations, forming a polymeric chain running along the c axis. The lattice water mol­ecule is situated on a twofold rotation axis, and links to the perchlorate anion via an O—H⋯O hydrogen bond. The long Ag⋯O separation of 3.200 (4) Å indicates a weak inter­action between the perchlorate anion and the Ag(I) cation. Weak C—H⋯O hydrogen bonding occurs between the chain and the lattice water mol­ecule and between the chain and perchlorate anions. Both five-membered rings of the L ligand display envelope conformations; in one five-membered ring, the flap C atom is disordered on opposite sides of the ring with occupancies of 0.65 and 0.35. International Union of Crystallography 2012-04-21 /pmc/articles/PMC3344364/ /pubmed/22590130 http://dx.doi.org/10.1107/S1600536812016406 Text en © Yeh et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yeh, Chun-Wei
Huang, Fu-Chang
Lin, Shui-Chuan
Jong, Ay
Suen, Maw-Cherng
catena-Poly[[silver(I)-μ-1,2-bis­(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane-κ(2) N:N′] perchlorate hemihydrate]
title catena-Poly[[silver(I)-μ-1,2-bis­(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane-κ(2) N:N′] perchlorate hemihydrate]
title_full catena-Poly[[silver(I)-μ-1,2-bis­(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane-κ(2) N:N′] perchlorate hemihydrate]
title_fullStr catena-Poly[[silver(I)-μ-1,2-bis­(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane-κ(2) N:N′] perchlorate hemihydrate]
title_full_unstemmed catena-Poly[[silver(I)-μ-1,2-bis­(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane-κ(2) N:N′] perchlorate hemihydrate]
title_short catena-Poly[[silver(I)-μ-1,2-bis­(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane-κ(2) N:N′] perchlorate hemihydrate]
title_sort catena-poly[[silver(i)-μ-1,2-bis­(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane-κ(2) n:n′] perchlorate hemihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344364/
https://www.ncbi.nlm.nih.gov/pubmed/22590130
http://dx.doi.org/10.1107/S1600536812016406
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