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catena-Poly[[(2-amino-1,3-benzothia­zole-6-carboxyl­ato-κ(2) O,O′)(2,2′-bipyridyl-κ(2) N,N′)cadmium]-μ-2-amino-1,3-benzothia­zole-6-carboxyl­ato-κ(3) N (1):O,O′]

In the title coordination polymer, [Cd(C(8)H(5)N(2)O(2)S)(2)(C(10)H(8)N(2))](n), the Cd(II) ion is coordinated by a bidentate 2,2-bipyridyl ligand, two O,O′-chelating 2-amino-1,3-benzothia­zole-6-carboxyl­ate (ABTC) ligands and one N-bonded ABTC ligand. The resulting CdN(3)O(4) coordination polyhedr...

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Autores principales: Gao, Dan, Fang, Xin, Zhang, Ke-Ke, Cai, Li-Mao, Wang, Jun-Dong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344366/
https://www.ncbi.nlm.nih.gov/pubmed/22590132
http://dx.doi.org/10.1107/S160053681201642X
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author Gao, Dan
Fang, Xin
Zhang, Ke-Ke
Cai, Li-Mao
Wang, Jun-Dong
author_facet Gao, Dan
Fang, Xin
Zhang, Ke-Ke
Cai, Li-Mao
Wang, Jun-Dong
author_sort Gao, Dan
collection PubMed
description In the title coordination polymer, [Cd(C(8)H(5)N(2)O(2)S)(2)(C(10)H(8)N(2))](n), the Cd(II) ion is coordinated by a bidentate 2,2-bipyridyl ligand, two O,O′-chelating 2-amino-1,3-benzothia­zole-6-carboxyl­ate (ABTC) ligands and one N-bonded ABTC ligand. The resulting CdN(3)O(4) coordination polyhedron approximates to a very distorted penta­gonal bipramid with one O and one N atom in axial positions. One of the ABTC ligands is bridging to an adjacent metal atom, generating an infinite chain propagating in [100]. A three-dimensional network is constructed from N—H⋯O and N—H⋯N hydrogen bonds and aromatic π–π stacking inter­actions [centroid–centroid separations = 3.641 (2) and 3.682 (3) Å].
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spelling pubmed-33443662012-05-15 catena-Poly[[(2-amino-1,3-benzothia­zole-6-carboxyl­ato-κ(2) O,O′)(2,2′-bipyridyl-κ(2) N,N′)cadmium]-μ-2-amino-1,3-benzothia­zole-6-carboxyl­ato-κ(3) N (1):O,O′] Gao, Dan Fang, Xin Zhang, Ke-Ke Cai, Li-Mao Wang, Jun-Dong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [Cd(C(8)H(5)N(2)O(2)S)(2)(C(10)H(8)N(2))](n), the Cd(II) ion is coordinated by a bidentate 2,2-bipyridyl ligand, two O,O′-chelating 2-amino-1,3-benzothia­zole-6-carboxyl­ate (ABTC) ligands and one N-bonded ABTC ligand. The resulting CdN(3)O(4) coordination polyhedron approximates to a very distorted penta­gonal bipramid with one O and one N atom in axial positions. One of the ABTC ligands is bridging to an adjacent metal atom, generating an infinite chain propagating in [100]. A three-dimensional network is constructed from N—H⋯O and N—H⋯N hydrogen bonds and aromatic π–π stacking inter­actions [centroid–centroid separations = 3.641 (2) and 3.682 (3) Å]. International Union of Crystallography 2012-04-21 /pmc/articles/PMC3344366/ /pubmed/22590132 http://dx.doi.org/10.1107/S160053681201642X Text en © Gao et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gao, Dan
Fang, Xin
Zhang, Ke-Ke
Cai, Li-Mao
Wang, Jun-Dong
catena-Poly[[(2-amino-1,3-benzothia­zole-6-carboxyl­ato-κ(2) O,O′)(2,2′-bipyridyl-κ(2) N,N′)cadmium]-μ-2-amino-1,3-benzothia­zole-6-carboxyl­ato-κ(3) N (1):O,O′]
title catena-Poly[[(2-amino-1,3-benzothia­zole-6-carboxyl­ato-κ(2) O,O′)(2,2′-bipyridyl-κ(2) N,N′)cadmium]-μ-2-amino-1,3-benzothia­zole-6-carboxyl­ato-κ(3) N (1):O,O′]
title_full catena-Poly[[(2-amino-1,3-benzothia­zole-6-carboxyl­ato-κ(2) O,O′)(2,2′-bipyridyl-κ(2) N,N′)cadmium]-μ-2-amino-1,3-benzothia­zole-6-carboxyl­ato-κ(3) N (1):O,O′]
title_fullStr catena-Poly[[(2-amino-1,3-benzothia­zole-6-carboxyl­ato-κ(2) O,O′)(2,2′-bipyridyl-κ(2) N,N′)cadmium]-μ-2-amino-1,3-benzothia­zole-6-carboxyl­ato-κ(3) N (1):O,O′]
title_full_unstemmed catena-Poly[[(2-amino-1,3-benzothia­zole-6-carboxyl­ato-κ(2) O,O′)(2,2′-bipyridyl-κ(2) N,N′)cadmium]-μ-2-amino-1,3-benzothia­zole-6-carboxyl­ato-κ(3) N (1):O,O′]
title_short catena-Poly[[(2-amino-1,3-benzothia­zole-6-carboxyl­ato-κ(2) O,O′)(2,2′-bipyridyl-κ(2) N,N′)cadmium]-μ-2-amino-1,3-benzothia­zole-6-carboxyl­ato-κ(3) N (1):O,O′]
title_sort catena-poly[[(2-amino-1,3-benzothia­zole-6-carboxyl­ato-κ(2) o,o′)(2,2′-bipyridyl-κ(2) n,n′)cadmium]-μ-2-amino-1,3-benzothia­zole-6-carboxyl­ato-κ(3) n (1):o,o′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344366/
https://www.ncbi.nlm.nih.gov/pubmed/22590132
http://dx.doi.org/10.1107/S160053681201642X
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