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catena-Poly[[(2-amino-1,3-benzothiazole-6-carboxylato-κ(2) O,O′)(2,2′-bipyridyl-κ(2) N,N′)cadmium]-μ-2-amino-1,3-benzothiazole-6-carboxylato-κ(3) N (1):O,O′]
In the title coordination polymer, [Cd(C(8)H(5)N(2)O(2)S)(2)(C(10)H(8)N(2))](n), the Cd(II) ion is coordinated by a bidentate 2,2-bipyridyl ligand, two O,O′-chelating 2-amino-1,3-benzothiazole-6-carboxylate (ABTC) ligands and one N-bonded ABTC ligand. The resulting CdN(3)O(4) coordination polyhedr...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344366/ https://www.ncbi.nlm.nih.gov/pubmed/22590132 http://dx.doi.org/10.1107/S160053681201642X |
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author | Gao, Dan Fang, Xin Zhang, Ke-Ke Cai, Li-Mao Wang, Jun-Dong |
author_facet | Gao, Dan Fang, Xin Zhang, Ke-Ke Cai, Li-Mao Wang, Jun-Dong |
author_sort | Gao, Dan |
collection | PubMed |
description | In the title coordination polymer, [Cd(C(8)H(5)N(2)O(2)S)(2)(C(10)H(8)N(2))](n), the Cd(II) ion is coordinated by a bidentate 2,2-bipyridyl ligand, two O,O′-chelating 2-amino-1,3-benzothiazole-6-carboxylate (ABTC) ligands and one N-bonded ABTC ligand. The resulting CdN(3)O(4) coordination polyhedron approximates to a very distorted pentagonal bipramid with one O and one N atom in axial positions. One of the ABTC ligands is bridging to an adjacent metal atom, generating an infinite chain propagating in [100]. A three-dimensional network is constructed from N—H⋯O and N—H⋯N hydrogen bonds and aromatic π–π stacking interactions [centroid–centroid separations = 3.641 (2) and 3.682 (3) Å]. |
format | Online Article Text |
id | pubmed-3344366 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33443662012-05-15 catena-Poly[[(2-amino-1,3-benzothiazole-6-carboxylato-κ(2) O,O′)(2,2′-bipyridyl-κ(2) N,N′)cadmium]-μ-2-amino-1,3-benzothiazole-6-carboxylato-κ(3) N (1):O,O′] Gao, Dan Fang, Xin Zhang, Ke-Ke Cai, Li-Mao Wang, Jun-Dong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [Cd(C(8)H(5)N(2)O(2)S)(2)(C(10)H(8)N(2))](n), the Cd(II) ion is coordinated by a bidentate 2,2-bipyridyl ligand, two O,O′-chelating 2-amino-1,3-benzothiazole-6-carboxylate (ABTC) ligands and one N-bonded ABTC ligand. The resulting CdN(3)O(4) coordination polyhedron approximates to a very distorted pentagonal bipramid with one O and one N atom in axial positions. One of the ABTC ligands is bridging to an adjacent metal atom, generating an infinite chain propagating in [100]. A three-dimensional network is constructed from N—H⋯O and N—H⋯N hydrogen bonds and aromatic π–π stacking interactions [centroid–centroid separations = 3.641 (2) and 3.682 (3) Å]. International Union of Crystallography 2012-04-21 /pmc/articles/PMC3344366/ /pubmed/22590132 http://dx.doi.org/10.1107/S160053681201642X Text en © Gao et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Gao, Dan Fang, Xin Zhang, Ke-Ke Cai, Li-Mao Wang, Jun-Dong catena-Poly[[(2-amino-1,3-benzothiazole-6-carboxylato-κ(2) O,O′)(2,2′-bipyridyl-κ(2) N,N′)cadmium]-μ-2-amino-1,3-benzothiazole-6-carboxylato-κ(3) N (1):O,O′] |
title |
catena-Poly[[(2-amino-1,3-benzothiazole-6-carboxylato-κ(2)
O,O′)(2,2′-bipyridyl-κ(2)
N,N′)cadmium]-μ-2-amino-1,3-benzothiazole-6-carboxylato-κ(3)
N
(1):O,O′] |
title_full |
catena-Poly[[(2-amino-1,3-benzothiazole-6-carboxylato-κ(2)
O,O′)(2,2′-bipyridyl-κ(2)
N,N′)cadmium]-μ-2-amino-1,3-benzothiazole-6-carboxylato-κ(3)
N
(1):O,O′] |
title_fullStr |
catena-Poly[[(2-amino-1,3-benzothiazole-6-carboxylato-κ(2)
O,O′)(2,2′-bipyridyl-κ(2)
N,N′)cadmium]-μ-2-amino-1,3-benzothiazole-6-carboxylato-κ(3)
N
(1):O,O′] |
title_full_unstemmed |
catena-Poly[[(2-amino-1,3-benzothiazole-6-carboxylato-κ(2)
O,O′)(2,2′-bipyridyl-κ(2)
N,N′)cadmium]-μ-2-amino-1,3-benzothiazole-6-carboxylato-κ(3)
N
(1):O,O′] |
title_short |
catena-Poly[[(2-amino-1,3-benzothiazole-6-carboxylato-κ(2)
O,O′)(2,2′-bipyridyl-κ(2)
N,N′)cadmium]-μ-2-amino-1,3-benzothiazole-6-carboxylato-κ(3)
N
(1):O,O′] |
title_sort | catena-poly[[(2-amino-1,3-benzothiazole-6-carboxylato-κ(2)
o,o′)(2,2′-bipyridyl-κ(2)
n,n′)cadmium]-μ-2-amino-1,3-benzothiazole-6-carboxylato-κ(3)
n
(1):o,o′] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344366/ https://www.ncbi.nlm.nih.gov/pubmed/22590132 http://dx.doi.org/10.1107/S160053681201642X |
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