Cargando…
Di-μ-bromido-bis({2-[(4,6-dimethylpyrimidin-2-yl)disulfanyl]-4,6-dimethylpyrimidine-κ(2) N (1),S (2)}copper(I))
The title dinuclear complex, [Cu(2)Br(2)(C(12)H(14)N(4)S(2))(2)], is located about an inversion center. The Cu(I) ion is coordinated in a distorted tetrahedral geometry by two bridging Br atoms in addition to an N and an S atom from the 2-[(4,6-dimethylpyrimidin-2-yl)disulfanyl]-4,6-dimethylpyri...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344368/ https://www.ncbi.nlm.nih.gov/pubmed/22590134 http://dx.doi.org/10.1107/S1600536812016315 |
Sumario: | The title dinuclear complex, [Cu(2)Br(2)(C(12)H(14)N(4)S(2))(2)], is located about an inversion center. The Cu(I) ion is coordinated in a distorted tetrahedral geometry by two bridging Br atoms in addition to an N and an S atom from the 2-[(4,6-dimethylpyrimidin-2-yl)disulfanyl]-4,6-dimethylpyrimidine ligand. In the crystal, π–π stacking interactions are observed with a centroid–centroid distance of 3.590 (2) Å. |
---|