Di-μ-bromido-bis­({2-[(4,6-dimethyl­pyrimidin-2-yl)disulfan­yl]-4,6-dimethyl­pyrimidine-κ(2) N (1),S (2)}copper(I))

The title dinuclear complex, [Cu(2)Br(2)(C(12)H(14)N(4)S(2))(2)], is located about an inversion center. The Cu(I) ion is coordinated in a distorted tetra­hedral geometry by two bridging Br atoms in addition to an N and an S atom from the 2-[(4,6-dimethyl­pyrimidin-2-yl)disulfan­yl]-4,6-dimethyl­pyri...

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Detalles Bibliográficos
Autores principales: Nimthong, Ruthairat, Pakawatchai, Chaveng, Wattanakanjana, Yupa
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344368/
https://www.ncbi.nlm.nih.gov/pubmed/22590134
http://dx.doi.org/10.1107/S1600536812016315
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author Nimthong, Ruthairat
Pakawatchai, Chaveng
Wattanakanjana, Yupa
author_facet Nimthong, Ruthairat
Pakawatchai, Chaveng
Wattanakanjana, Yupa
author_sort Nimthong, Ruthairat
collection PubMed
description The title dinuclear complex, [Cu(2)Br(2)(C(12)H(14)N(4)S(2))(2)], is located about an inversion center. The Cu(I) ion is coordinated in a distorted tetra­hedral geometry by two bridging Br atoms in addition to an N and an S atom from the 2-[(4,6-dimethyl­pyrimidin-2-yl)disulfan­yl]-4,6-dimethyl­pyrimidine ligand. In the crystal, π–π stacking inter­actions are observed with a centroid–centroid distance of 3.590 (2) Å.
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spelling pubmed-33443682012-05-15 Di-μ-bromido-bis­({2-[(4,6-dimethyl­pyrimidin-2-yl)disulfan­yl]-4,6-dimethyl­pyrimidine-κ(2) N (1),S (2)}copper(I)) Nimthong, Ruthairat Pakawatchai, Chaveng Wattanakanjana, Yupa Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title dinuclear complex, [Cu(2)Br(2)(C(12)H(14)N(4)S(2))(2)], is located about an inversion center. The Cu(I) ion is coordinated in a distorted tetra­hedral geometry by two bridging Br atoms in addition to an N and an S atom from the 2-[(4,6-dimethyl­pyrimidin-2-yl)disulfan­yl]-4,6-dimethyl­pyrimidine ligand. In the crystal, π–π stacking inter­actions are observed with a centroid–centroid distance of 3.590 (2) Å. International Union of Crystallography 2012-04-21 /pmc/articles/PMC3344368/ /pubmed/22590134 http://dx.doi.org/10.1107/S1600536812016315 Text en © Nimthong et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Nimthong, Ruthairat
Pakawatchai, Chaveng
Wattanakanjana, Yupa
Di-μ-bromido-bis­({2-[(4,6-dimethyl­pyrimidin-2-yl)disulfan­yl]-4,6-dimethyl­pyrimidine-κ(2) N (1),S (2)}copper(I))
title Di-μ-bromido-bis­({2-[(4,6-dimethyl­pyrimidin-2-yl)disulfan­yl]-4,6-dimethyl­pyrimidine-κ(2) N (1),S (2)}copper(I))
title_full Di-μ-bromido-bis­({2-[(4,6-dimethyl­pyrimidin-2-yl)disulfan­yl]-4,6-dimethyl­pyrimidine-κ(2) N (1),S (2)}copper(I))
title_fullStr Di-μ-bromido-bis­({2-[(4,6-dimethyl­pyrimidin-2-yl)disulfan­yl]-4,6-dimethyl­pyrimidine-κ(2) N (1),S (2)}copper(I))
title_full_unstemmed Di-μ-bromido-bis­({2-[(4,6-dimethyl­pyrimidin-2-yl)disulfan­yl]-4,6-dimethyl­pyrimidine-κ(2) N (1),S (2)}copper(I))
title_short Di-μ-bromido-bis­({2-[(4,6-dimethyl­pyrimidin-2-yl)disulfan­yl]-4,6-dimethyl­pyrimidine-κ(2) N (1),S (2)}copper(I))
title_sort di-μ-bromido-bis­({2-[(4,6-dimethyl­pyrimidin-2-yl)disulfan­yl]-4,6-dimethyl­pyrimidine-κ(2) n (1),s (2)}copper(i))
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344368/
https://www.ncbi.nlm.nih.gov/pubmed/22590134
http://dx.doi.org/10.1107/S1600536812016315
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AT wattanakanjanayupa dimbromidobis246dimethylpyrimidin2yldisulfanyl46dimethylpyrimidinek2n1s2copperi

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