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N-Ferrocenymethyl-N-phenylpropionamide
In the title compound, [Fe(C(5)H(5))(C(15)H(16)NO)], the two cyclopentadienyl (Cp) rings are nearly parallel to each other, forming a dihedral angle of 3.7 (1)°, and adopt a staggered conformation. The amide group is almost perpendicular to the plane of the substituted Cp ring, with a C—N—C—C tors...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344370/ https://www.ncbi.nlm.nih.gov/pubmed/22590136 http://dx.doi.org/10.1107/S1600536812016303 |
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author | Khelef, Abdelhamid Terki, Belgacem Mahboub, Mohammed Sadok Lanez, Touhami |
author_facet | Khelef, Abdelhamid Terki, Belgacem Mahboub, Mohammed Sadok Lanez, Touhami |
author_sort | Khelef, Abdelhamid |
collection | PubMed |
description | In the title compound, [Fe(C(5)H(5))(C(15)H(16)NO)], the two cyclopentadienyl (Cp) rings are nearly parallel to each other, forming a dihedral angle of 3.7 (1)°, and adopt a staggered conformation. The amide group is almost perpendicular to the plane of the substituted Cp ring, with a C—N—C—C torsion angle of 101.3 (2)°, and the N and O atoms in the ethanoyl group are coplanar, with a C—N—C—O torsion angle of −0.7 (3)°. Weak C—H⋯O hydrogen bonds link adjacent molecules. |
format | Online Article Text |
id | pubmed-3344370 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33443702012-05-15 N-Ferrocenymethyl-N-phenylpropionamide Khelef, Abdelhamid Terki, Belgacem Mahboub, Mohammed Sadok Lanez, Touhami Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(C(5)H(5))(C(15)H(16)NO)], the two cyclopentadienyl (Cp) rings are nearly parallel to each other, forming a dihedral angle of 3.7 (1)°, and adopt a staggered conformation. The amide group is almost perpendicular to the plane of the substituted Cp ring, with a C—N—C—C torsion angle of 101.3 (2)°, and the N and O atoms in the ethanoyl group are coplanar, with a C—N—C—O torsion angle of −0.7 (3)°. Weak C—H⋯O hydrogen bonds link adjacent molecules. International Union of Crystallography 2012-04-21 /pmc/articles/PMC3344370/ /pubmed/22590136 http://dx.doi.org/10.1107/S1600536812016303 Text en © Khelef et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Khelef, Abdelhamid Terki, Belgacem Mahboub, Mohammed Sadok Lanez, Touhami N-Ferrocenymethyl-N-phenylpropionamide |
title |
N-Ferrocenymethyl-N-phenylpropionamide |
title_full |
N-Ferrocenymethyl-N-phenylpropionamide |
title_fullStr |
N-Ferrocenymethyl-N-phenylpropionamide |
title_full_unstemmed |
N-Ferrocenymethyl-N-phenylpropionamide |
title_short |
N-Ferrocenymethyl-N-phenylpropionamide |
title_sort | n-ferrocenymethyl-n-phenylpropionamide |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344370/ https://www.ncbi.nlm.nih.gov/pubmed/22590136 http://dx.doi.org/10.1107/S1600536812016303 |
work_keys_str_mv | AT khelefabdelhamid nferrocenymethylnphenylpropionamide AT terkibelgacem nferrocenymethylnphenylpropionamide AT mahboubmohammedsadok nferrocenymethylnphenylpropionamide AT laneztouhami nferrocenymethylnphenylpropionamide |