Cargando…
catena-Poly[[[aqua(1,10-phenanthroline-κ(2) N,N′)manganese(II)]-{μ-4,4′-[(4-carboxybenzyl)nitrilo]dibenzoato-κ(4) O,O′:O′′,O′′′}] monohydrate]
The title compound, {[Mn(C(22)H(15)NO(6))(C(12)H(8)N(2))(H(2)O]·H(2)O}(n), was obtained under solvothermal conditions. The Mn(2+) cation exhibits a distorted pentagonal–bipyramidal MnN(2)O(5) coordination sphere with the water O atom and one of the phenanthroline N atoms in the axial positions. The...
| Autores principales: | , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344372/ https://www.ncbi.nlm.nih.gov/pubmed/22590138 http://dx.doi.org/10.1107/S1600536812016819 |
| _version_ | 1782231977765634048 |
|---|---|
| author | Hu, Jin-Song Jing, Lei Song, Xiao-Ming He, Jie |
| author_facet | Hu, Jin-Song Jing, Lei Song, Xiao-Ming He, Jie |
| author_sort | Hu, Jin-Song |
| collection | PubMed |
| description | The title compound, {[Mn(C(22)H(15)NO(6))(C(12)H(8)N(2))(H(2)O]·H(2)O}(n), was obtained under solvothermal conditions. The Mn(2+) cation exhibits a distorted pentagonal–bipyramidal MnN(2)O(5) coordination sphere with the water O atom and one of the phenanthroline N atoms in the axial positions. The cation is bridged by the doubly deprotonated 4,4′-[(4-carboxybenzyl)nitrilo]dibenzoate ligand, generating a polymeric chain parallel to [100]. O—H⋯O hydrogen bonding, as well as π–π interactions between neighbouring phenanthroline ligands, with centroid–centroid distances of 3.695 (1) Å, lead to the construction of a three-dimensional network. |
| format | Online Article Text |
| id | pubmed-3344372 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33443722012-05-15 catena-Poly[[[aqua(1,10-phenanthroline-κ(2) N,N′)manganese(II)]-{μ-4,4′-[(4-carboxybenzyl)nitrilo]dibenzoato-κ(4) O,O′:O′′,O′′′}] monohydrate] Hu, Jin-Song Jing, Lei Song, Xiao-Ming He, Jie Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {[Mn(C(22)H(15)NO(6))(C(12)H(8)N(2))(H(2)O]·H(2)O}(n), was obtained under solvothermal conditions. The Mn(2+) cation exhibits a distorted pentagonal–bipyramidal MnN(2)O(5) coordination sphere with the water O atom and one of the phenanthroline N atoms in the axial positions. The cation is bridged by the doubly deprotonated 4,4′-[(4-carboxybenzyl)nitrilo]dibenzoate ligand, generating a polymeric chain parallel to [100]. O—H⋯O hydrogen bonding, as well as π–π interactions between neighbouring phenanthroline ligands, with centroid–centroid distances of 3.695 (1) Å, lead to the construction of a three-dimensional network. International Union of Crystallography 2012-04-21 /pmc/articles/PMC3344372/ /pubmed/22590138 http://dx.doi.org/10.1107/S1600536812016819 Text en © Hu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Hu, Jin-Song Jing, Lei Song, Xiao-Ming He, Jie catena-Poly[[[aqua(1,10-phenanthroline-κ(2) N,N′)manganese(II)]-{μ-4,4′-[(4-carboxybenzyl)nitrilo]dibenzoato-κ(4) O,O′:O′′,O′′′}] monohydrate] |
| title |
catena-Poly[[[aqua(1,10-phenanthroline-κ(2)
N,N′)manganese(II)]-{μ-4,4′-[(4-carboxybenzyl)nitrilo]dibenzoato-κ(4)
O,O′:O′′,O′′′}] monohydrate] |
| title_full |
catena-Poly[[[aqua(1,10-phenanthroline-κ(2)
N,N′)manganese(II)]-{μ-4,4′-[(4-carboxybenzyl)nitrilo]dibenzoato-κ(4)
O,O′:O′′,O′′′}] monohydrate] |
| title_fullStr |
catena-Poly[[[aqua(1,10-phenanthroline-κ(2)
N,N′)manganese(II)]-{μ-4,4′-[(4-carboxybenzyl)nitrilo]dibenzoato-κ(4)
O,O′:O′′,O′′′}] monohydrate] |
| title_full_unstemmed |
catena-Poly[[[aqua(1,10-phenanthroline-κ(2)
N,N′)manganese(II)]-{μ-4,4′-[(4-carboxybenzyl)nitrilo]dibenzoato-κ(4)
O,O′:O′′,O′′′}] monohydrate] |
| title_short |
catena-Poly[[[aqua(1,10-phenanthroline-κ(2)
N,N′)manganese(II)]-{μ-4,4′-[(4-carboxybenzyl)nitrilo]dibenzoato-κ(4)
O,O′:O′′,O′′′}] monohydrate] |
| title_sort | catena-poly[[[aqua(1,10-phenanthroline-κ(2)
n,n′)manganese(ii)]-{μ-4,4′-[(4-carboxybenzyl)nitrilo]dibenzoato-κ(4)
o,o′:o′′,o′′′}] monohydrate] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344372/ https://www.ncbi.nlm.nih.gov/pubmed/22590138 http://dx.doi.org/10.1107/S1600536812016819 |
| work_keys_str_mv | AT hujinsong catenapolyaqua110phenanthrolinek2nnmanganeseiim444carboxybenzylnitrilodibenzoatok4oooomonohydrate AT jinglei catenapolyaqua110phenanthrolinek2nnmanganeseiim444carboxybenzylnitrilodibenzoatok4oooomonohydrate AT songxiaoming catenapolyaqua110phenanthrolinek2nnmanganeseiim444carboxybenzylnitrilodibenzoatok4oooomonohydrate AT hejie catenapolyaqua110phenanthrolinek2nnmanganeseiim444carboxybenzylnitrilodibenzoatok4oooomonohydrate |