catena-Poly[[diaqua­bis­(2-ethyl-1H-imidazole-κN (3))cadmium]-μ-sulfato-κ(2) O:O′]

In the title one-dimensional coordination polymer, [Cd(SO(4))(C(5)H(8)N(2))(2)(H(2)O)(2)](n), the Cd(II) atom (site symmetry 2) is coordinated by two sulfate O atoms, two water mol­ecules and two 2-ethyl­imidazole ligands in a distorted cis-CdN(2)O(4) octa­hedral geometry. The water mol­ecules have...

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Detalles Bibliográficos
Autor principal: Yu, Chua-Hua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344375/
https://www.ncbi.nlm.nih.gov/pubmed/22590141
http://dx.doi.org/10.1107/S1600536812017059
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author Yu, Chua-Hua
author_facet Yu, Chua-Hua
author_sort Yu, Chua-Hua
collection PubMed
description In the title one-dimensional coordination polymer, [Cd(SO(4))(C(5)H(8)N(2))(2)(H(2)O)(2)](n), the Cd(II) atom (site symmetry 2) is coordinated by two sulfate O atoms, two water mol­ecules and two 2-ethyl­imidazole ligands in a distorted cis-CdN(2)O(4) octa­hedral geometry. The water mol­ecules have a cis disposition. The bridging sulfate ions (site symmetry 2) link the Cd(II) ions into a polymeric chain extending along [001]. The chains are linked by N—H⋯O and O—H⋯O hydrogen bonds. The terminal –CH(3) group of the ligand is disordered over two orientations in a 0.61 (5):0.39 (5) ratio.
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spelling pubmed-33443752012-05-15 catena-Poly[[diaqua­bis­(2-ethyl-1H-imidazole-κN (3))cadmium]-μ-sulfato-κ(2) O:O′] Yu, Chua-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title one-dimensional coordination polymer, [Cd(SO(4))(C(5)H(8)N(2))(2)(H(2)O)(2)](n), the Cd(II) atom (site symmetry 2) is coordinated by two sulfate O atoms, two water mol­ecules and two 2-ethyl­imidazole ligands in a distorted cis-CdN(2)O(4) octa­hedral geometry. The water mol­ecules have a cis disposition. The bridging sulfate ions (site symmetry 2) link the Cd(II) ions into a polymeric chain extending along [001]. The chains are linked by N—H⋯O and O—H⋯O hydrogen bonds. The terminal –CH(3) group of the ligand is disordered over two orientations in a 0.61 (5):0.39 (5) ratio. International Union of Crystallography 2012-04-21 /pmc/articles/PMC3344375/ /pubmed/22590141 http://dx.doi.org/10.1107/S1600536812017059 Text en © Chua-Hua Yu 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yu, Chua-Hua
catena-Poly[[diaqua­bis­(2-ethyl-1H-imidazole-κN (3))cadmium]-μ-sulfato-κ(2) O:O′]
title catena-Poly[[diaqua­bis­(2-ethyl-1H-imidazole-κN (3))cadmium]-μ-sulfato-κ(2) O:O′]
title_full catena-Poly[[diaqua­bis­(2-ethyl-1H-imidazole-κN (3))cadmium]-μ-sulfato-κ(2) O:O′]
title_fullStr catena-Poly[[diaqua­bis­(2-ethyl-1H-imidazole-κN (3))cadmium]-μ-sulfato-κ(2) O:O′]
title_full_unstemmed catena-Poly[[diaqua­bis­(2-ethyl-1H-imidazole-κN (3))cadmium]-μ-sulfato-κ(2) O:O′]
title_short catena-Poly[[diaqua­bis­(2-ethyl-1H-imidazole-κN (3))cadmium]-μ-sulfato-κ(2) O:O′]
title_sort catena-poly[[diaqua­bis­(2-ethyl-1h-imidazole-κn (3))cadmium]-μ-sulfato-κ(2) o:o′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344375/
https://www.ncbi.nlm.nih.gov/pubmed/22590141
http://dx.doi.org/10.1107/S1600536812017059
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