Cargando…
catena-Poly[[[aquabis(1H-imidazole-κN (3))copper(II)]-μ-furan-2,5-dicarboxylato-κ(2) O (2):O (5)] trihydrate]
In the title cooridnation polymer, {[Cu(C(6)H(2)O(5))(C(3)H(4)N(2))(2)(H(2)O)]·3H(2)O}(n), an infinite chain is formed along [001] by linking of the Cu(C(3)N(2)H(4))(2)(H(2)O) entities with two bridging monodentate carboxylate groups of two different furan-2,5-dicarboxylate dianions. The geometry...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344379/ https://www.ncbi.nlm.nih.gov/pubmed/22590145 http://dx.doi.org/10.1107/S1600536812016856 |
Sumario: | In the title cooridnation polymer, {[Cu(C(6)H(2)O(5))(C(3)H(4)N(2))(2)(H(2)O)]·3H(2)O}(n), an infinite chain is formed along [001] by linking of the Cu(C(3)N(2)H(4))(2)(H(2)O) entities with two bridging monodentate carboxylate groups of two different furan-2,5-dicarboxylate dianions. The geometry of the Cu(2+) ion is a square-based pyramid with the water atom in the apical position and the ligand O and N atoms in a trans orientation. The dihedral angle between the imidazole planes is 83.96 (14)°. O(w)–H⋯O and N(i)–H⋯O (w = water and i = imidazole) hydrogen bonds help to establish the packing. |
---|