catena-Poly[[[aqua­bis­(1H-imidazole-κN (3))copper(II)]-μ-furan-2,5-di­car­boxylato-κ(2) O (2):O (5)] trihydrate]

In the title cooridnation polymer, {[Cu(C(6)H(2)O(5))(C(3)H(4)N(2))(2)(H(2)O)]·3H(2)O}(n), an infinite chain is formed along [001] by linking of the Cu(C(3)N(2)H(4))(2)(H(2)O) entities with two bridging monodentate carboxyl­ate groups of two different furan-2,5-dicarboxyl­ate dianions. The geometry...

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Detalles Bibliográficos
Autores principales: Li, Ya-Feng, Xu, Yue, Qin, Xiao-Lin, Gao, Wen-Yuan, Gao, Yue
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344379/
https://www.ncbi.nlm.nih.gov/pubmed/22590145
http://dx.doi.org/10.1107/S1600536812016856
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author Li, Ya-Feng
Xu, Yue
Qin, Xiao-Lin
Gao, Wen-Yuan
Gao, Yue
author_facet Li, Ya-Feng
Xu, Yue
Qin, Xiao-Lin
Gao, Wen-Yuan
Gao, Yue
author_sort Li, Ya-Feng
collection PubMed
description In the title cooridnation polymer, {[Cu(C(6)H(2)O(5))(C(3)H(4)N(2))(2)(H(2)O)]·3H(2)O}(n), an infinite chain is formed along [001] by linking of the Cu(C(3)N(2)H(4))(2)(H(2)O) entities with two bridging monodentate carboxyl­ate groups of two different furan-2,5-dicarboxyl­ate dianions. The geometry of the Cu(2+) ion is a square-based pyramid with the water atom in the apical position and the ligand O and N atoms in a trans orientation. The dihedral angle between the imidazole planes is 83.96 (14)°. O(w)–H⋯O and N(i)–H⋯O (w = water and i = imidazole) hydrogen bonds help to establish the packing.
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spelling pubmed-33443792012-05-15 catena-Poly[[[aqua­bis­(1H-imidazole-κN (3))copper(II)]-μ-furan-2,5-di­car­boxylato-κ(2) O (2):O (5)] trihydrate] Li, Ya-Feng Xu, Yue Qin, Xiao-Lin Gao, Wen-Yuan Gao, Yue Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title cooridnation polymer, {[Cu(C(6)H(2)O(5))(C(3)H(4)N(2))(2)(H(2)O)]·3H(2)O}(n), an infinite chain is formed along [001] by linking of the Cu(C(3)N(2)H(4))(2)(H(2)O) entities with two bridging monodentate carboxyl­ate groups of two different furan-2,5-dicarboxyl­ate dianions. The geometry of the Cu(2+) ion is a square-based pyramid with the water atom in the apical position and the ligand O and N atoms in a trans orientation. The dihedral angle between the imidazole planes is 83.96 (14)°. O(w)–H⋯O and N(i)–H⋯O (w = water and i = imidazole) hydrogen bonds help to establish the packing. International Union of Crystallography 2012-04-21 /pmc/articles/PMC3344379/ /pubmed/22590145 http://dx.doi.org/10.1107/S1600536812016856 Text en © Li et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Ya-Feng
Xu, Yue
Qin, Xiao-Lin
Gao, Wen-Yuan
Gao, Yue
catena-Poly[[[aqua­bis­(1H-imidazole-κN (3))copper(II)]-μ-furan-2,5-di­car­boxylato-κ(2) O (2):O (5)] trihydrate]
title catena-Poly[[[aqua­bis­(1H-imidazole-κN (3))copper(II)]-μ-furan-2,5-di­car­boxylato-κ(2) O (2):O (5)] trihydrate]
title_full catena-Poly[[[aqua­bis­(1H-imidazole-κN (3))copper(II)]-μ-furan-2,5-di­car­boxylato-κ(2) O (2):O (5)] trihydrate]
title_fullStr catena-Poly[[[aqua­bis­(1H-imidazole-κN (3))copper(II)]-μ-furan-2,5-di­car­boxylato-κ(2) O (2):O (5)] trihydrate]
title_full_unstemmed catena-Poly[[[aqua­bis­(1H-imidazole-κN (3))copper(II)]-μ-furan-2,5-di­car­boxylato-κ(2) O (2):O (5)] trihydrate]
title_short catena-Poly[[[aqua­bis­(1H-imidazole-κN (3))copper(II)]-μ-furan-2,5-di­car­boxylato-κ(2) O (2):O (5)] trihydrate]
title_sort catena-poly[[[aqua­bis­(1h-imidazole-κn (3))copper(ii)]-μ-furan-2,5-di­car­boxylato-κ(2) o (2):o (5)] trihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344379/
https://www.ncbi.nlm.nih.gov/pubmed/22590145
http://dx.doi.org/10.1107/S1600536812016856
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