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Bis{S-benzyl 3-[(6-methylpyridin-2-yl)methylidene]dithiocarbazato}nickel(II)
The asymmetric unit of the title compound, [Ni(C(15)H(14)N(3)S(2))(2)], consists of two independent molecules with similar configurations. Each Ni(2+) cation is coordinated in a cis-mode by two tridentate N,N′,S-chelating Schiff base ligands, creating a distorted octahedron [the smallest angle bei...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344386/ https://www.ncbi.nlm.nih.gov/pubmed/22590148 http://dx.doi.org/10.1107/S1600536812017333 |
| _version_ | 1782231980067258368 |
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| author | Ravoof, Thahira Begum S. A. Omar, Siti Aminah Mohamed Tahir, Mohamed Ibrahim Crouse, Karen A. |
| author_facet | Ravoof, Thahira Begum S. A. Omar, Siti Aminah Mohamed Tahir, Mohamed Ibrahim Crouse, Karen A. |
| author_sort | Ravoof, Thahira Begum S. A. |
| collection | PubMed |
| description | The asymmetric unit of the title compound, [Ni(C(15)H(14)N(3)S(2))(2)], consists of two independent molecules with similar configurations. Each Ni(2+) cation is coordinated in a cis-mode by two tridentate N,N′,S-chelating Schiff base ligands, creating a distorted octahedron [the smallest angle being 77.57 (7)° and the widest being 168.97 (7)° for one molecule, and 78.04 (7) and 167.55 (7)° for the second molecule]. The dihedral angle between the mean coordination planes of the two ligands is 86.76 (7)° for one and 89.99 (7)° for the second molecule. π–π interactions between neighbouring pyridine rings with plane-to-plane distances of 3.540 (1) and 3.704 (1) Å are observed. |
| format | Online Article Text |
| id | pubmed-3344386 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33443862012-05-15 Bis{S-benzyl 3-[(6-methylpyridin-2-yl)methylidene]dithiocarbazato}nickel(II) Ravoof, Thahira Begum S. A. Omar, Siti Aminah Mohamed Tahir, Mohamed Ibrahim Crouse, Karen A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Ni(C(15)H(14)N(3)S(2))(2)], consists of two independent molecules with similar configurations. Each Ni(2+) cation is coordinated in a cis-mode by two tridentate N,N′,S-chelating Schiff base ligands, creating a distorted octahedron [the smallest angle being 77.57 (7)° and the widest being 168.97 (7)° for one molecule, and 78.04 (7) and 167.55 (7)° for the second molecule]. The dihedral angle between the mean coordination planes of the two ligands is 86.76 (7)° for one and 89.99 (7)° for the second molecule. π–π interactions between neighbouring pyridine rings with plane-to-plane distances of 3.540 (1) and 3.704 (1) Å are observed. International Union of Crystallography 2012-04-25 /pmc/articles/PMC3344386/ /pubmed/22590148 http://dx.doi.org/10.1107/S1600536812017333 Text en © Ravoof et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Ravoof, Thahira Begum S. A. Omar, Siti Aminah Mohamed Tahir, Mohamed Ibrahim Crouse, Karen A. Bis{S-benzyl 3-[(6-methylpyridin-2-yl)methylidene]dithiocarbazato}nickel(II) |
| title | Bis{S-benzyl 3-[(6-methylpyridin-2-yl)methylidene]dithiocarbazato}nickel(II) |
| title_full | Bis{S-benzyl 3-[(6-methylpyridin-2-yl)methylidene]dithiocarbazato}nickel(II) |
| title_fullStr | Bis{S-benzyl 3-[(6-methylpyridin-2-yl)methylidene]dithiocarbazato}nickel(II) |
| title_full_unstemmed | Bis{S-benzyl 3-[(6-methylpyridin-2-yl)methylidene]dithiocarbazato}nickel(II) |
| title_short | Bis{S-benzyl 3-[(6-methylpyridin-2-yl)methylidene]dithiocarbazato}nickel(II) |
| title_sort | bis{s-benzyl 3-[(6-methylpyridin-2-yl)methylidene]dithiocarbazato}nickel(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344386/ https://www.ncbi.nlm.nih.gov/pubmed/22590148 http://dx.doi.org/10.1107/S1600536812017333 |
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