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1-Cyanomethyl-1,4-diazoniabicyclo[2.2.2]octane tetrachloridocobaltate(II)
In the title salt, (C(8)H(15)N(3))[CoCl(4)], the four chloride anions coordinate the Co(II) ion in a distorted tetrahedral geometry. In the crystal, N—H⋯Cl hydrogen bonds link cations and anions into chains running along the c axis. The crystal packing is further stabilized by weak C—H⋯Cl and C—H⋯N...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344387/ https://www.ncbi.nlm.nih.gov/pubmed/22590149 http://dx.doi.org/10.1107/S1600536812017187 |
| _version_ | 1782231980289556480 |
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| author | Zhang, Yi Zhu, Bo-Han |
| author_facet | Zhang, Yi Zhu, Bo-Han |
| author_sort | Zhang, Yi |
| collection | PubMed |
| description | In the title salt, (C(8)H(15)N(3))[CoCl(4)], the four chloride anions coordinate the Co(II) ion in a distorted tetrahedral geometry. In the crystal, N—H⋯Cl hydrogen bonds link cations and anions into chains running along the c axis. The crystal packing is further stabilized by weak C—H⋯Cl and C—H⋯N interactions. |
| format | Online Article Text |
| id | pubmed-3344387 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33443872012-05-15 1-Cyanomethyl-1,4-diazoniabicyclo[2.2.2]octane tetrachloridocobaltate(II) Zhang, Yi Zhu, Bo-Han Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, (C(8)H(15)N(3))[CoCl(4)], the four chloride anions coordinate the Co(II) ion in a distorted tetrahedral geometry. In the crystal, N—H⋯Cl hydrogen bonds link cations and anions into chains running along the c axis. The crystal packing is further stabilized by weak C—H⋯Cl and C—H⋯N interactions. International Union of Crystallography 2012-04-25 /pmc/articles/PMC3344387/ /pubmed/22590149 http://dx.doi.org/10.1107/S1600536812017187 Text en © Zhang and Zhu 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zhang, Yi Zhu, Bo-Han 1-Cyanomethyl-1,4-diazoniabicyclo[2.2.2]octane tetrachloridocobaltate(II) |
| title | 1-Cyanomethyl-1,4-diazoniabicyclo[2.2.2]octane tetrachloridocobaltate(II) |
| title_full | 1-Cyanomethyl-1,4-diazoniabicyclo[2.2.2]octane tetrachloridocobaltate(II) |
| title_fullStr | 1-Cyanomethyl-1,4-diazoniabicyclo[2.2.2]octane tetrachloridocobaltate(II) |
| title_full_unstemmed | 1-Cyanomethyl-1,4-diazoniabicyclo[2.2.2]octane tetrachloridocobaltate(II) |
| title_short | 1-Cyanomethyl-1,4-diazoniabicyclo[2.2.2]octane tetrachloridocobaltate(II) |
| title_sort | 1-cyanomethyl-1,4-diazoniabicyclo[2.2.2]octane tetrachloridocobaltate(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344387/ https://www.ncbi.nlm.nih.gov/pubmed/22590149 http://dx.doi.org/10.1107/S1600536812017187 |
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