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[4,4′-(Ethane-1,2-diyldinitrilo)­bis­(pent-2-en-2-olato)]copper(II) 0.25-hydrate

In the title compound, [Cu(C(12)H(18)N(2)O(2))]·0.25H(2)O, the coordination of the O,N,N′,O′-tetra­dentate ligand results in a cis-CuN(2)O(2) square-planar geometry for the metal ion and the presence of two six-membered and one five-membered chelate rings. The complete complex mol­ecule is close to...

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Detalles Bibliográficos
Autores principales: Aslam, Muhammad, Anis, Itrat, Afza, Nighat, Hussain, Ajaz, Ahmed, Waseem, Arshad, Muhammad Nadeem
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344391/
https://www.ncbi.nlm.nih.gov/pubmed/22590153
http://dx.doi.org/10.1107/S1600536812017102
Descripción
Sumario:In the title compound, [Cu(C(12)H(18)N(2)O(2))]·0.25H(2)O, the coordination of the O,N,N′,O′-tetra­dentate ligand results in a cis-CuN(2)O(2) square-planar geometry for the metal ion and the presence of two six-membered and one five-membered chelate rings. The complete complex mol­ecule is close to planar (r.m.s. deviation = 0.047 Å). The uncoordinated water mol­ecule (O-atom site symmetry 2) was modelled as half occupied. In the crystal, C—H⋯O(w) and O(w)—H⋯O (w = water) hydrogen bonds link the components into layers parallel to ab plane.