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[4,4′-(Ethane-1,2-diyldinitrilo)bis(pent-2-en-2-olato)]copper(II) 0.25-hydrate
In the title compound, [Cu(C(12)H(18)N(2)O(2))]·0.25H(2)O, the coordination of the O,N,N′,O′-tetradentate ligand results in a cis-CuN(2)O(2) square-planar geometry for the metal ion and the presence of two six-membered and one five-membered chelate rings. The complete complex molecule is close to...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344391/ https://www.ncbi.nlm.nih.gov/pubmed/22590153 http://dx.doi.org/10.1107/S1600536812017102 |
| _version_ | 1782231981193428992 |
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| author | Aslam, Muhammad Anis, Itrat Afza, Nighat Hussain, Ajaz Ahmed, Waseem Arshad, Muhammad Nadeem |
| author_facet | Aslam, Muhammad Anis, Itrat Afza, Nighat Hussain, Ajaz Ahmed, Waseem Arshad, Muhammad Nadeem |
| author_sort | Aslam, Muhammad |
| collection | PubMed |
| description | In the title compound, [Cu(C(12)H(18)N(2)O(2))]·0.25H(2)O, the coordination of the O,N,N′,O′-tetradentate ligand results in a cis-CuN(2)O(2) square-planar geometry for the metal ion and the presence of two six-membered and one five-membered chelate rings. The complete complex molecule is close to planar (r.m.s. deviation = 0.047 Å). The uncoordinated water molecule (O-atom site symmetry 2) was modelled as half occupied. In the crystal, C—H⋯O(w) and O(w)—H⋯O (w = water) hydrogen bonds link the components into layers parallel to ab plane. |
| format | Online Article Text |
| id | pubmed-3344391 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33443912012-05-15 [4,4′-(Ethane-1,2-diyldinitrilo)bis(pent-2-en-2-olato)]copper(II) 0.25-hydrate Aslam, Muhammad Anis, Itrat Afza, Nighat Hussain, Ajaz Ahmed, Waseem Arshad, Muhammad Nadeem Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(12)H(18)N(2)O(2))]·0.25H(2)O, the coordination of the O,N,N′,O′-tetradentate ligand results in a cis-CuN(2)O(2) square-planar geometry for the metal ion and the presence of two six-membered and one five-membered chelate rings. The complete complex molecule is close to planar (r.m.s. deviation = 0.047 Å). The uncoordinated water molecule (O-atom site symmetry 2) was modelled as half occupied. In the crystal, C—H⋯O(w) and O(w)—H⋯O (w = water) hydrogen bonds link the components into layers parallel to ab plane. International Union of Crystallography 2012-04-25 /pmc/articles/PMC3344391/ /pubmed/22590153 http://dx.doi.org/10.1107/S1600536812017102 Text en © Aslam et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Aslam, Muhammad Anis, Itrat Afza, Nighat Hussain, Ajaz Ahmed, Waseem Arshad, Muhammad Nadeem [4,4′-(Ethane-1,2-diyldinitrilo)bis(pent-2-en-2-olato)]copper(II) 0.25-hydrate |
| title | [4,4′-(Ethane-1,2-diyldinitrilo)bis(pent-2-en-2-olato)]copper(II) 0.25-hydrate |
| title_full | [4,4′-(Ethane-1,2-diyldinitrilo)bis(pent-2-en-2-olato)]copper(II) 0.25-hydrate |
| title_fullStr | [4,4′-(Ethane-1,2-diyldinitrilo)bis(pent-2-en-2-olato)]copper(II) 0.25-hydrate |
| title_full_unstemmed | [4,4′-(Ethane-1,2-diyldinitrilo)bis(pent-2-en-2-olato)]copper(II) 0.25-hydrate |
| title_short | [4,4′-(Ethane-1,2-diyldinitrilo)bis(pent-2-en-2-olato)]copper(II) 0.25-hydrate |
| title_sort | [4,4′-(ethane-1,2-diyldinitrilo)bis(pent-2-en-2-olato)]copper(ii) 0.25-hydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344391/ https://www.ncbi.nlm.nih.gov/pubmed/22590153 http://dx.doi.org/10.1107/S1600536812017102 |
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