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Poly[(acetato-κ(2) O,O′)aqua(μ(4)-1H-benzimidazole-5,6-dicarboxylato-κ(6) N (3):O (5),O (5′):O (5),O (6):O (6′))cerium(III)]
In the title compound, [Ce(C(9)H(4)N(2)O(4))(C(2)H(3)O(2))(H(2)O)](n), the Ce(III) ion is coordinated by five O atoms and one N atom from four 1H-benzimidazole-5,6-dicarboxylato (L) ligands and by two O atoms from an acetate ligand and one aqua ligand, forming a slightly distorted tricapped trigona...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344394/ https://www.ncbi.nlm.nih.gov/pubmed/22590156 http://dx.doi.org/10.1107/S1600536812017503 |
| _version_ | 1782231981852983296 |
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| author | Chen, Jinhua Wang, Yuezhu Zheng, Chun Luo, Yifan |
| author_facet | Chen, Jinhua Wang, Yuezhu Zheng, Chun Luo, Yifan |
| author_sort | Chen, Jinhua |
| collection | PubMed |
| description | In the title compound, [Ce(C(9)H(4)N(2)O(4))(C(2)H(3)O(2))(H(2)O)](n), the Ce(III) ion is coordinated by five O atoms and one N atom from four 1H-benzimidazole-5,6-dicarboxylato (L) ligands and by two O atoms from an acetate ligand and one aqua ligand, forming a slightly distorted tricapped trigonal–prismatic geometry. The L ligands are bridging, forming a layered polymer parallel to (010). In the crystal, O—H⋯O and N—H⋯O hydrogen bonds connect the polymer layers into a three-dimensional network. |
| format | Online Article Text |
| id | pubmed-3344394 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33443942012-05-15 Poly[(acetato-κ(2) O,O′)aqua(μ(4)-1H-benzimidazole-5,6-dicarboxylato-κ(6) N (3):O (5),O (5′):O (5),O (6):O (6′))cerium(III)] Chen, Jinhua Wang, Yuezhu Zheng, Chun Luo, Yifan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ce(C(9)H(4)N(2)O(4))(C(2)H(3)O(2))(H(2)O)](n), the Ce(III) ion is coordinated by five O atoms and one N atom from four 1H-benzimidazole-5,6-dicarboxylato (L) ligands and by two O atoms from an acetate ligand and one aqua ligand, forming a slightly distorted tricapped trigonal–prismatic geometry. The L ligands are bridging, forming a layered polymer parallel to (010). In the crystal, O—H⋯O and N—H⋯O hydrogen bonds connect the polymer layers into a three-dimensional network. International Union of Crystallography 2012-04-25 /pmc/articles/PMC3344394/ /pubmed/22590156 http://dx.doi.org/10.1107/S1600536812017503 Text en © Chen et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Chen, Jinhua Wang, Yuezhu Zheng, Chun Luo, Yifan Poly[(acetato-κ(2) O,O′)aqua(μ(4)-1H-benzimidazole-5,6-dicarboxylato-κ(6) N (3):O (5),O (5′):O (5),O (6):O (6′))cerium(III)] |
| title | Poly[(acetato-κ(2)
O,O′)aqua(μ(4)-1H-benzimidazole-5,6-dicarboxylato-κ(6)
N
(3):O
(5),O
(5′):O
(5),O
(6):O
(6′))cerium(III)] |
| title_full | Poly[(acetato-κ(2)
O,O′)aqua(μ(4)-1H-benzimidazole-5,6-dicarboxylato-κ(6)
N
(3):O
(5),O
(5′):O
(5),O
(6):O
(6′))cerium(III)] |
| title_fullStr | Poly[(acetato-κ(2)
O,O′)aqua(μ(4)-1H-benzimidazole-5,6-dicarboxylato-κ(6)
N
(3):O
(5),O
(5′):O
(5),O
(6):O
(6′))cerium(III)] |
| title_full_unstemmed | Poly[(acetato-κ(2)
O,O′)aqua(μ(4)-1H-benzimidazole-5,6-dicarboxylato-κ(6)
N
(3):O
(5),O
(5′):O
(5),O
(6):O
(6′))cerium(III)] |
| title_short | Poly[(acetato-κ(2)
O,O′)aqua(μ(4)-1H-benzimidazole-5,6-dicarboxylato-κ(6)
N
(3):O
(5),O
(5′):O
(5),O
(6):O
(6′))cerium(III)] |
| title_sort | poly[(acetato-κ(2)
o,o′)aqua(μ(4)-1h-benzimidazole-5,6-dicarboxylato-κ(6)
n
(3):o
(5),o
(5′):o
(5),o
(6):o
(6′))cerium(iii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344394/ https://www.ncbi.nlm.nih.gov/pubmed/22590156 http://dx.doi.org/10.1107/S1600536812017503 |
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