Aqua­trichlorido(1-cyano­methyl-4-aza-1-azoniabicyclo­[2.2.2]octane-κN (4))copper(II) monohydrate

The asymmetric unit of the title compound, [CuCl(3)(C(8)H(14)N(3))(H(2)O)]·H(2)O, comprises a neutral complex and a mol­ecule of free water. The complex contains coordinated Cu(II) ions, with Cu—Cl distances ranging from 2.3471 (8) to 2.4011 (8) Å, and with Cu—N and Cu—O distances of 2.0775 (19) and...

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Detalles Bibliográficos
Autores principales: Zhou, Qinqin, Zhang, Yi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344395/
https://www.ncbi.nlm.nih.gov/pubmed/22590157
http://dx.doi.org/10.1107/S1600536812017205
Descripción
Sumario:The asymmetric unit of the title compound, [CuCl(3)(C(8)H(14)N(3))(H(2)O)]·H(2)O, comprises a neutral complex and a mol­ecule of free water. The complex contains coordinated Cu(II) ions, with Cu—Cl distances ranging from 2.3471 (8) to 2.4011 (8) Å, and with Cu—N and Cu—O distances of 2.0775 (19) and 2.0048 (18) Å, respectively. The resulting coordination polyhedron is a trigonal bipyramid with the Cl atoms in the equatorial plane. In the crystal, O—H⋯Cl and O—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional structure.

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