Aqua­trichlorido(1-cyano­methyl-4-aza-1-azoniabicyclo­[2.2.2]octane-κN (4))copper(II) monohydrate

The asymmetric unit of the title compound, [CuCl(3)(C(8)H(14)N(3))(H(2)O)]·H(2)O, comprises a neutral complex and a mol­ecule of free water. The complex contains coordinated Cu(II) ions, with Cu—Cl distances ranging from 2.3471 (8) to 2.4011 (8) Å, and with Cu—N and Cu—O distances of 2.0775 (19) and...

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Detalles Bibliográficos
Autores principales: Zhou, Qinqin, Zhang, Yi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344395/
https://www.ncbi.nlm.nih.gov/pubmed/22590157
http://dx.doi.org/10.1107/S1600536812017205
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author Zhou, Qinqin
Zhang, Yi
author_facet Zhou, Qinqin
Zhang, Yi
author_sort Zhou, Qinqin
collection PubMed
description The asymmetric unit of the title compound, [CuCl(3)(C(8)H(14)N(3))(H(2)O)]·H(2)O, comprises a neutral complex and a mol­ecule of free water. The complex contains coordinated Cu(II) ions, with Cu—Cl distances ranging from 2.3471 (8) to 2.4011 (8) Å, and with Cu—N and Cu—O distances of 2.0775 (19) and 2.0048 (18) Å, respectively. The resulting coordination polyhedron is a trigonal bipyramid with the Cl atoms in the equatorial plane. In the crystal, O—H⋯Cl and O—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional structure.
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spelling pubmed-33443952012-05-15 Aqua­trichlorido(1-cyano­methyl-4-aza-1-azoniabicyclo­[2.2.2]octane-κN (4))copper(II) monohydrate Zhou, Qinqin Zhang, Yi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [CuCl(3)(C(8)H(14)N(3))(H(2)O)]·H(2)O, comprises a neutral complex and a mol­ecule of free water. The complex contains coordinated Cu(II) ions, with Cu—Cl distances ranging from 2.3471 (8) to 2.4011 (8) Å, and with Cu—N and Cu—O distances of 2.0775 (19) and 2.0048 (18) Å, respectively. The resulting coordination polyhedron is a trigonal bipyramid with the Cl atoms in the equatorial plane. In the crystal, O—H⋯Cl and O—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional structure. International Union of Crystallography 2012-04-25 /pmc/articles/PMC3344395/ /pubmed/22590157 http://dx.doi.org/10.1107/S1600536812017205 Text en © Zhou and Zhang 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhou, Qinqin
Zhang, Yi
Aqua­trichlorido(1-cyano­methyl-4-aza-1-azoniabicyclo­[2.2.2]octane-κN (4))copper(II) monohydrate
title Aqua­trichlorido(1-cyano­methyl-4-aza-1-azoniabicyclo­[2.2.2]octane-κN (4))copper(II) monohydrate
title_full Aqua­trichlorido(1-cyano­methyl-4-aza-1-azoniabicyclo­[2.2.2]octane-κN (4))copper(II) monohydrate
title_fullStr Aqua­trichlorido(1-cyano­methyl-4-aza-1-azoniabicyclo­[2.2.2]octane-κN (4))copper(II) monohydrate
title_full_unstemmed Aqua­trichlorido(1-cyano­methyl-4-aza-1-azoniabicyclo­[2.2.2]octane-κN (4))copper(II) monohydrate
title_short Aqua­trichlorido(1-cyano­methyl-4-aza-1-azoniabicyclo­[2.2.2]octane-κN (4))copper(II) monohydrate
title_sort aqua­trichlorido(1-cyano­methyl-4-aza-1-azoniabicyclo­[2.2.2]octane-κn (4))copper(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344395/
https://www.ncbi.nlm.nih.gov/pubmed/22590157
http://dx.doi.org/10.1107/S1600536812017205
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