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(2,2′-Bipyrimidine-κ(2) N (1),N (1′))bis­(thio­cyanato-κN)platinum(II)

In the title complex, [Pt(NCS)(2)(C(8)H(6)N(4))], the Pt(II) ion is four-coordinated in a distorted square-planar environment defined by two pyrimidine N atoms derived from a chelating 2,2′-bipyrimidine (bpym) ligand and two mutually cis N atoms from two SCN(−) anions. The thio­cyanate ligands are a...

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Detalles Bibliográficos
Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344397/
https://www.ncbi.nlm.nih.gov/pubmed/22590159
http://dx.doi.org/10.1107/S1600536812017552
Descripción
Sumario:In the title complex, [Pt(NCS)(2)(C(8)H(6)N(4))], the Pt(II) ion is four-coordinated in a distorted square-planar environment defined by two pyrimidine N atoms derived from a chelating 2,2′-bipyrimidine (bpym) ligand and two mutually cis N atoms from two SCN(−) anions. The thio­cyanate ligands are almost linear, displaying N—C—S bond angles of 178.6 (11) and 173.7 (11)°, and the N atoms are slightly bent coordinated to the Pt atom with Pt—N—C bond angles of 172.7 (9) and 160.4 (10)°. In the crystal, mol­ecules are held together by C—H⋯S hydrogen bonds. Intra­molecular C—H⋯N hydrogen bonds are also observed