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(2,2′-Bipyrimidine-κ(2) N (1),N (1′))bis(thiocyanato-κN)platinum(II)
In the title complex, [Pt(NCS)(2)(C(8)H(6)N(4))], the Pt(II) ion is four-coordinated in a distorted square-planar environment defined by two pyrimidine N atoms derived from a chelating 2,2′-bipyrimidine (bpym) ligand and two mutually cis N atoms from two SCN(−) anions. The thiocyanate ligands are a...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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International Union of Crystallography
2012
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344397/ https://www.ncbi.nlm.nih.gov/pubmed/22590159 http://dx.doi.org/10.1107/S1600536812017552 |
| _version_ | 1782231982523023360 |
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| author | Ha, Kwang |
| author_facet | Ha, Kwang |
| author_sort | Ha, Kwang |
| collection | PubMed |
| description | In the title complex, [Pt(NCS)(2)(C(8)H(6)N(4))], the Pt(II) ion is four-coordinated in a distorted square-planar environment defined by two pyrimidine N atoms derived from a chelating 2,2′-bipyrimidine (bpym) ligand and two mutually cis N atoms from two SCN(−) anions. The thiocyanate ligands are almost linear, displaying N—C—S bond angles of 178.6 (11) and 173.7 (11)°, and the N atoms are slightly bent coordinated to the Pt atom with Pt—N—C bond angles of 172.7 (9) and 160.4 (10)°. In the crystal, molecules are held together by C—H⋯S hydrogen bonds. Intramolecular C—H⋯N hydrogen bonds are also observed |
| format | Online Article Text |
| id | pubmed-3344397 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33443972012-05-15 (2,2′-Bipyrimidine-κ(2) N (1),N (1′))bis(thiocyanato-κN)platinum(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Pt(NCS)(2)(C(8)H(6)N(4))], the Pt(II) ion is four-coordinated in a distorted square-planar environment defined by two pyrimidine N atoms derived from a chelating 2,2′-bipyrimidine (bpym) ligand and two mutually cis N atoms from two SCN(−) anions. The thiocyanate ligands are almost linear, displaying N—C—S bond angles of 178.6 (11) and 173.7 (11)°, and the N atoms are slightly bent coordinated to the Pt atom with Pt—N—C bond angles of 172.7 (9) and 160.4 (10)°. In the crystal, molecules are held together by C—H⋯S hydrogen bonds. Intramolecular C—H⋯N hydrogen bonds are also observed International Union of Crystallography 2012-04-25 /pmc/articles/PMC3344397/ /pubmed/22590159 http://dx.doi.org/10.1107/S1600536812017552 Text en © Kwang Ha 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Ha, Kwang (2,2′-Bipyrimidine-κ(2) N (1),N (1′))bis(thiocyanato-κN)platinum(II) |
| title | (2,2′-Bipyrimidine-κ(2)
N
(1),N
(1′))bis(thiocyanato-κN)platinum(II) |
| title_full | (2,2′-Bipyrimidine-κ(2)
N
(1),N
(1′))bis(thiocyanato-κN)platinum(II) |
| title_fullStr | (2,2′-Bipyrimidine-κ(2)
N
(1),N
(1′))bis(thiocyanato-κN)platinum(II) |
| title_full_unstemmed | (2,2′-Bipyrimidine-κ(2)
N
(1),N
(1′))bis(thiocyanato-κN)platinum(II) |
| title_short | (2,2′-Bipyrimidine-κ(2)
N
(1),N
(1′))bis(thiocyanato-κN)platinum(II) |
| title_sort | (2,2′-bipyrimidine-κ(2)
n
(1),n
(1′))bis(thiocyanato-κn)platinum(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344397/ https://www.ncbi.nlm.nih.gov/pubmed/22590159 http://dx.doi.org/10.1107/S1600536812017552 |
| work_keys_str_mv | AT hakwang 22bipyrimidinek2n1n1bisthiocyanatoknplatinumii |