(Acetato-κO)(2-bromo-6-{[3-(dimethyl­aza­nium­yl)propyl­imino-κN]meth­yl}phenolato-κO)(thio­cyanato-κN)zinc

In the title compound, [Zn(CH(3)COO)(NCS)(C(12)H(17)BrN(2)O)], the Zn(II) atom is four-coordinated in a distorted tetra­hedral geometry, binding to a phenolate O and an imine N atom of the Schiff base ligand, the O atom of an acetate ligand and one thio­cyanate N atom. In the crystal, mol­ecules are...

Descripción completa

Detalles Bibliográficos
Autor principal: Han, Cheng-Li
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344398/
https://www.ncbi.nlm.nih.gov/pubmed/22590160
http://dx.doi.org/10.1107/S1600536812017564
_version_ 1782231982765244416
author Han, Cheng-Li
author_facet Han, Cheng-Li
author_sort Han, Cheng-Li
collection PubMed
description In the title compound, [Zn(CH(3)COO)(NCS)(C(12)H(17)BrN(2)O)], the Zn(II) atom is four-coordinated in a distorted tetra­hedral geometry, binding to a phenolate O and an imine N atom of the Schiff base ligand, the O atom of an acetate ligand and one thio­cyanate N atom. In the crystal, mol­ecules are linked via pairs of N—H⋯O hydrogen bonds, forming inversion dimers.
format Online
Article
Text
id pubmed-3344398
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33443982012-05-15 (Acetato-κO)(2-bromo-6-{[3-(dimethyl­aza­nium­yl)propyl­imino-κN]meth­yl}phenolato-κO)(thio­cyanato-κN)zinc Han, Cheng-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(CH(3)COO)(NCS)(C(12)H(17)BrN(2)O)], the Zn(II) atom is four-coordinated in a distorted tetra­hedral geometry, binding to a phenolate O and an imine N atom of the Schiff base ligand, the O atom of an acetate ligand and one thio­cyanate N atom. In the crystal, mol­ecules are linked via pairs of N—H⋯O hydrogen bonds, forming inversion dimers. International Union of Crystallography 2012-04-25 /pmc/articles/PMC3344398/ /pubmed/22590160 http://dx.doi.org/10.1107/S1600536812017564 Text en © Cheng-Li Han 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Han, Cheng-Li
(Acetato-κO)(2-bromo-6-{[3-(dimethyl­aza­nium­yl)propyl­imino-κN]meth­yl}phenolato-κO)(thio­cyanato-κN)zinc
title (Acetato-κO)(2-bromo-6-{[3-(dimethyl­aza­nium­yl)propyl­imino-κN]meth­yl}phenolato-κO)(thio­cyanato-κN)zinc
title_full (Acetato-κO)(2-bromo-6-{[3-(dimethyl­aza­nium­yl)propyl­imino-κN]meth­yl}phenolato-κO)(thio­cyanato-κN)zinc
title_fullStr (Acetato-κO)(2-bromo-6-{[3-(dimethyl­aza­nium­yl)propyl­imino-κN]meth­yl}phenolato-κO)(thio­cyanato-κN)zinc
title_full_unstemmed (Acetato-κO)(2-bromo-6-{[3-(dimethyl­aza­nium­yl)propyl­imino-κN]meth­yl}phenolato-κO)(thio­cyanato-κN)zinc
title_short (Acetato-κO)(2-bromo-6-{[3-(dimethyl­aza­nium­yl)propyl­imino-κN]meth­yl}phenolato-κO)(thio­cyanato-κN)zinc
title_sort (acetato-κo)(2-bromo-6-{[3-(dimethyl­aza­nium­yl)propyl­imino-κn]meth­yl}phenolato-κo)(thio­cyanato-κn)zinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344398/
https://www.ncbi.nlm.nih.gov/pubmed/22590160
http://dx.doi.org/10.1107/S1600536812017564
work_keys_str_mv AT hanchengli acetatoko2bromo63dimethylazaniumylpropyliminoknmethylphenolatokothiocyanatoknzinc

Ejemplares similares