N-Benzyl-N,N-dimethyl­octa­decan-1-aminium (2-thioxo-1,3-dithiole-4,5-dithiol­ato-κ(2) S (4),S (5))nickelate(III)

The asymmtric unit of the title compound, (C(27)H(50)N)[Ni(C(3)S(5))(2)], contains two N-benzyl-N,N-dimethyl­octa­decan-1-aminium cations, [BDA](+), and two [Ni(dmit)(2)](−) anions (dmit = 2-thioxo-1,3-dithiole-4,5-dithiol­ate). The C(18) chains in both cations adopt almost ideal extended conformati...

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Detalles Bibliográficos
Autor principal: Liu, Guang-Xiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344399/
https://www.ncbi.nlm.nih.gov/pubmed/22590161
http://dx.doi.org/10.1107/S1600536812016698
Descripción
Sumario:The asymmtric unit of the title compound, (C(27)H(50)N)[Ni(C(3)S(5))(2)], contains two N-benzyl-N,N-dimethyl­octa­decan-1-aminium cations, [BDA](+), and two [Ni(dmit)(2)](−) anions (dmit = 2-thioxo-1,3-dithiole-4,5-dithiol­ate). The C(18) chains in both cations adopt almost ideal extended conformations. The Ni(III) atoms are coordinated by two S,S′-bidentate ligands, generating NiS(4) square planes. Short Ni⋯S [3.734 (2) Å] and S⋯S contacts [3.5438 (15) Å] occur in the crystal structure; if these are considered to be bonding inter­actions, then infinite sheets of anions parallel to (111) arise.

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