N-Benzyl-N,N-dimethyl­octa­decan-1-aminium (2-thioxo-1,3-dithiole-4,5-dithiol­ato-κ(2) S (4),S (5))nickelate(III)

The asymmtric unit of the title compound, (C(27)H(50)N)[Ni(C(3)S(5))(2)], contains two N-benzyl-N,N-dimethyl­octa­decan-1-aminium cations, [BDA](+), and two [Ni(dmit)(2)](−) anions (dmit = 2-thioxo-1,3-dithiole-4,5-dithiol­ate). The C(18) chains in both cations adopt almost ideal extended conformati...

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Detalles Bibliográficos
Autor principal: Liu, Guang-Xiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344399/
https://www.ncbi.nlm.nih.gov/pubmed/22590161
http://dx.doi.org/10.1107/S1600536812016698
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author Liu, Guang-Xiang
author_facet Liu, Guang-Xiang
author_sort Liu, Guang-Xiang
collection PubMed
description The asymmtric unit of the title compound, (C(27)H(50)N)[Ni(C(3)S(5))(2)], contains two N-benzyl-N,N-dimethyl­octa­decan-1-aminium cations, [BDA](+), and two [Ni(dmit)(2)](−) anions (dmit = 2-thioxo-1,3-dithiole-4,5-dithiol­ate). The C(18) chains in both cations adopt almost ideal extended conformations. The Ni(III) atoms are coordinated by two S,S′-bidentate ligands, generating NiS(4) square planes. Short Ni⋯S [3.734 (2) Å] and S⋯S contacts [3.5438 (15) Å] occur in the crystal structure; if these are considered to be bonding inter­actions, then infinite sheets of anions parallel to (111) arise.
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spelling pubmed-33443992012-05-15 N-Benzyl-N,N-dimethyl­octa­decan-1-aminium (2-thioxo-1,3-dithiole-4,5-dithiol­ato-κ(2) S (4),S (5))nickelate(III) Liu, Guang-Xiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmtric unit of the title compound, (C(27)H(50)N)[Ni(C(3)S(5))(2)], contains two N-benzyl-N,N-dimethyl­octa­decan-1-aminium cations, [BDA](+), and two [Ni(dmit)(2)](−) anions (dmit = 2-thioxo-1,3-dithiole-4,5-dithiol­ate). The C(18) chains in both cations adopt almost ideal extended conformations. The Ni(III) atoms are coordinated by two S,S′-bidentate ligands, generating NiS(4) square planes. Short Ni⋯S [3.734 (2) Å] and S⋯S contacts [3.5438 (15) Å] occur in the crystal structure; if these are considered to be bonding inter­actions, then infinite sheets of anions parallel to (111) arise. International Union of Crystallography 2012-04-25 /pmc/articles/PMC3344399/ /pubmed/22590161 http://dx.doi.org/10.1107/S1600536812016698 Text en © Guang-Xiang Liu 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Guang-Xiang
N-Benzyl-N,N-dimethyl­octa­decan-1-aminium (2-thioxo-1,3-dithiole-4,5-dithiol­ato-κ(2) S (4),S (5))nickelate(III)
title N-Benzyl-N,N-dimethyl­octa­decan-1-aminium (2-thioxo-1,3-dithiole-4,5-dithiol­ato-κ(2) S (4),S (5))nickelate(III)
title_full N-Benzyl-N,N-dimethyl­octa­decan-1-aminium (2-thioxo-1,3-dithiole-4,5-dithiol­ato-κ(2) S (4),S (5))nickelate(III)
title_fullStr N-Benzyl-N,N-dimethyl­octa­decan-1-aminium (2-thioxo-1,3-dithiole-4,5-dithiol­ato-κ(2) S (4),S (5))nickelate(III)
title_full_unstemmed N-Benzyl-N,N-dimethyl­octa­decan-1-aminium (2-thioxo-1,3-dithiole-4,5-dithiol­ato-κ(2) S (4),S (5))nickelate(III)
title_short N-Benzyl-N,N-dimethyl­octa­decan-1-aminium (2-thioxo-1,3-dithiole-4,5-dithiol­ato-κ(2) S (4),S (5))nickelate(III)
title_sort n-benzyl-n,n-dimethyl­octa­decan-1-aminium (2-thioxo-1,3-dithiole-4,5-dithiol­ato-κ(2) s (4),s (5))nickelate(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344399/
https://www.ncbi.nlm.nih.gov/pubmed/22590161
http://dx.doi.org/10.1107/S1600536812016698
work_keys_str_mv AT liuguangxiang nbenzylnndimethyloctadecan1aminium2thioxo13dithiole45dithiolatok2s4s5nickelateiii

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