Bis(3-methyl­anilinium) hexa­chlorido­stannate(IV) dihydrate

In the title compound, (C(7)H(10)N)(2)[SnCl(6)]·2H(2)O, the Sn(IV) atom lies on a site with symmetry 2/m. One of the Cl atoms lies on a mirror plane and the 3-methyl­anilinium cation is also situated on a mirror plane. The water mol­ecule is located on a twofold rotation axis. The H atoms of the met...

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Detalles Bibliográficos
Autor principal: Liu, Ming-Liang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344401/
https://www.ncbi.nlm.nih.gov/pubmed/22590163
http://dx.doi.org/10.1107/S1600536812017618
Descripción
Sumario:In the title compound, (C(7)H(10)N)(2)[SnCl(6)]·2H(2)O, the Sn(IV) atom lies on a site with symmetry 2/m. One of the Cl atoms lies on a mirror plane and the 3-methyl­anilinium cation is also situated on a mirror plane. The water mol­ecule is located on a twofold rotation axis. The H atoms of the methyl and ammonium groups and the solvent water mol­ecule are disordered by symmetry. In the crystal, N—H⋯Cl, O—H⋯Cl and N—H⋯O hydrogen bonds connect the organic cations, the inorganic octahedrally shaped anions and the water mol­ecules.

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