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Bis(3-methylanilinium) hexachloridostannate(IV) dihydrate
In the title compound, (C(7)H(10)N)(2)[SnCl(6)]·2H(2)O, the Sn(IV) atom lies on a site with symmetry 2/m. One of the Cl atoms lies on a mirror plane and the 3-methylanilinium cation is also situated on a mirror plane. The water molecule is located on a twofold rotation axis. The H atoms of the met...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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International Union of Crystallography
2012
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344401/ https://www.ncbi.nlm.nih.gov/pubmed/22590163 http://dx.doi.org/10.1107/S1600536812017618 |
| _version_ | 1782231983432138752 |
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| author | Liu, Ming-Liang |
| author_facet | Liu, Ming-Liang |
| author_sort | Liu, Ming-Liang |
| collection | PubMed |
| description | In the title compound, (C(7)H(10)N)(2)[SnCl(6)]·2H(2)O, the Sn(IV) atom lies on a site with symmetry 2/m. One of the Cl atoms lies on a mirror plane and the 3-methylanilinium cation is also situated on a mirror plane. The water molecule is located on a twofold rotation axis. The H atoms of the methyl and ammonium groups and the solvent water molecule are disordered by symmetry. In the crystal, N—H⋯Cl, O—H⋯Cl and N—H⋯O hydrogen bonds connect the organic cations, the inorganic octahedrally shaped anions and the water molecules. |
| format | Online Article Text |
| id | pubmed-3344401 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33444012012-05-15 Bis(3-methylanilinium) hexachloridostannate(IV) dihydrate Liu, Ming-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(7)H(10)N)(2)[SnCl(6)]·2H(2)O, the Sn(IV) atom lies on a site with symmetry 2/m. One of the Cl atoms lies on a mirror plane and the 3-methylanilinium cation is also situated on a mirror plane. The water molecule is located on a twofold rotation axis. The H atoms of the methyl and ammonium groups and the solvent water molecule are disordered by symmetry. In the crystal, N—H⋯Cl, O—H⋯Cl and N—H⋯O hydrogen bonds connect the organic cations, the inorganic octahedrally shaped anions and the water molecules. International Union of Crystallography 2012-04-28 /pmc/articles/PMC3344401/ /pubmed/22590163 http://dx.doi.org/10.1107/S1600536812017618 Text en © Ming-Liang Liu 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Liu, Ming-Liang Bis(3-methylanilinium) hexachloridostannate(IV) dihydrate |
| title | Bis(3-methylanilinium) hexachloridostannate(IV) dihydrate |
| title_full | Bis(3-methylanilinium) hexachloridostannate(IV) dihydrate |
| title_fullStr | Bis(3-methylanilinium) hexachloridostannate(IV) dihydrate |
| title_full_unstemmed | Bis(3-methylanilinium) hexachloridostannate(IV) dihydrate |
| title_short | Bis(3-methylanilinium) hexachloridostannate(IV) dihydrate |
| title_sort | bis(3-methylanilinium) hexachloridostannate(iv) dihydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344401/ https://www.ncbi.nlm.nih.gov/pubmed/22590163 http://dx.doi.org/10.1107/S1600536812017618 |
| work_keys_str_mv | AT liumingliang bis3methylaniliniumhexachloridostannateivdihydrate |