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Poly[[chloridodimethanol(μ(3)-pyridine-2,3-dicarboxyl­ato)europium(III)] methanol monosolvate]

The asymmetric unit of the title compound, {[Eu(C(7)H(3)NO(4))Cl(CH(3)OH)(2)]·CH(3)OH}(n), contains one Eu(III) ion, one pyridine 2,3-dicarboxylate dianion (PDC), two CH(3)OH mol­ecules coordinating to the metal atom, one coordinating chloride and one lattice occluded CH(3)OH mol­ecule. In the cryst...

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Detalles Bibliográficos
Autores principales: Wu, Dayu, Chen, Liyang, Wu, Genhua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344402/
https://www.ncbi.nlm.nih.gov/pubmed/22590164
http://dx.doi.org/10.1107/S1600536812017862
Descripción
Sumario:The asymmetric unit of the title compound, {[Eu(C(7)H(3)NO(4))Cl(CH(3)OH)(2)]·CH(3)OH}(n), contains one Eu(III) ion, one pyridine 2,3-dicarboxylate dianion (PDC), two CH(3)OH mol­ecules coordinating to the metal atom, one coordinating chloride and one lattice occluded CH(3)OH mol­ecule. In the crystal, each PDC anion coordinates to three adjacent Eu(III) ions by the pyridine N and O atoms of the carboxyl­ate groups. The Eu(III) cation is eightfold coordinated by four carboxyl­ate O atoms, one pyridine N atom, two MeOH and one chloride anion in the form of a distorted polyhedron. Extended coordination of the PDC ligand lead to the formation of a two-dimensional coordination polymer parallel to (10-1).