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Poly[[chloridodimethanol(μ(3)-pyridine-2,3-dicarboxylato)europium(III)] methanol monosolvate]
The asymmetric unit of the title compound, {[Eu(C(7)H(3)NO(4))Cl(CH(3)OH)(2)]·CH(3)OH}(n), contains one Eu(III) ion, one pyridine 2,3-dicarboxylate dianion (PDC), two CH(3)OH molecules coordinating to the metal atom, one coordinating chloride and one lattice occluded CH(3)OH molecule. In the cryst...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344402/ https://www.ncbi.nlm.nih.gov/pubmed/22590164 http://dx.doi.org/10.1107/S1600536812017862 |
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author | Wu, Dayu Chen, Liyang Wu, Genhua |
author_facet | Wu, Dayu Chen, Liyang Wu, Genhua |
author_sort | Wu, Dayu |
collection | PubMed |
description | The asymmetric unit of the title compound, {[Eu(C(7)H(3)NO(4))Cl(CH(3)OH)(2)]·CH(3)OH}(n), contains one Eu(III) ion, one pyridine 2,3-dicarboxylate dianion (PDC), two CH(3)OH molecules coordinating to the metal atom, one coordinating chloride and one lattice occluded CH(3)OH molecule. In the crystal, each PDC anion coordinates to three adjacent Eu(III) ions by the pyridine N and O atoms of the carboxylate groups. The Eu(III) cation is eightfold coordinated by four carboxylate O atoms, one pyridine N atom, two MeOH and one chloride anion in the form of a distorted polyhedron. Extended coordination of the PDC ligand lead to the formation of a two-dimensional coordination polymer parallel to (10-1). |
format | Online Article Text |
id | pubmed-3344402 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33444022012-05-15 Poly[[chloridodimethanol(μ(3)-pyridine-2,3-dicarboxylato)europium(III)] methanol monosolvate] Wu, Dayu Chen, Liyang Wu, Genhua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, {[Eu(C(7)H(3)NO(4))Cl(CH(3)OH)(2)]·CH(3)OH}(n), contains one Eu(III) ion, one pyridine 2,3-dicarboxylate dianion (PDC), two CH(3)OH molecules coordinating to the metal atom, one coordinating chloride and one lattice occluded CH(3)OH molecule. In the crystal, each PDC anion coordinates to three adjacent Eu(III) ions by the pyridine N and O atoms of the carboxylate groups. The Eu(III) cation is eightfold coordinated by four carboxylate O atoms, one pyridine N atom, two MeOH and one chloride anion in the form of a distorted polyhedron. Extended coordination of the PDC ligand lead to the formation of a two-dimensional coordination polymer parallel to (10-1). International Union of Crystallography 2012-04-28 /pmc/articles/PMC3344402/ /pubmed/22590164 http://dx.doi.org/10.1107/S1600536812017862 Text en © Wu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wu, Dayu Chen, Liyang Wu, Genhua Poly[[chloridodimethanol(μ(3)-pyridine-2,3-dicarboxylato)europium(III)] methanol monosolvate] |
title | Poly[[chloridodimethanol(μ(3)-pyridine-2,3-dicarboxylato)europium(III)] methanol monosolvate] |
title_full | Poly[[chloridodimethanol(μ(3)-pyridine-2,3-dicarboxylato)europium(III)] methanol monosolvate] |
title_fullStr | Poly[[chloridodimethanol(μ(3)-pyridine-2,3-dicarboxylato)europium(III)] methanol monosolvate] |
title_full_unstemmed | Poly[[chloridodimethanol(μ(3)-pyridine-2,3-dicarboxylato)europium(III)] methanol monosolvate] |
title_short | Poly[[chloridodimethanol(μ(3)-pyridine-2,3-dicarboxylato)europium(III)] methanol monosolvate] |
title_sort | poly[[chloridodimethanol(μ(3)-pyridine-2,3-dicarboxylato)europium(iii)] methanol monosolvate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344402/ https://www.ncbi.nlm.nih.gov/pubmed/22590164 http://dx.doi.org/10.1107/S1600536812017862 |
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