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Poly[[chloridodimethanol(μ(3)-pyridine-2,3-dicarboxyl­ato)europium(III)] methanol monosolvate]

The asymmetric unit of the title compound, {[Eu(C(7)H(3)NO(4))Cl(CH(3)OH)(2)]·CH(3)OH}(n), contains one Eu(III) ion, one pyridine 2,3-dicarboxylate dianion (PDC), two CH(3)OH mol­ecules coordinating to the metal atom, one coordinating chloride and one lattice occluded CH(3)OH mol­ecule. In the cryst...

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Detalles Bibliográficos
Autores principales: Wu, Dayu, Chen, Liyang, Wu, Genhua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344402/
https://www.ncbi.nlm.nih.gov/pubmed/22590164
http://dx.doi.org/10.1107/S1600536812017862
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author Wu, Dayu
Chen, Liyang
Wu, Genhua
author_facet Wu, Dayu
Chen, Liyang
Wu, Genhua
author_sort Wu, Dayu
collection PubMed
description The asymmetric unit of the title compound, {[Eu(C(7)H(3)NO(4))Cl(CH(3)OH)(2)]·CH(3)OH}(n), contains one Eu(III) ion, one pyridine 2,3-dicarboxylate dianion (PDC), two CH(3)OH mol­ecules coordinating to the metal atom, one coordinating chloride and one lattice occluded CH(3)OH mol­ecule. In the crystal, each PDC anion coordinates to three adjacent Eu(III) ions by the pyridine N and O atoms of the carboxyl­ate groups. The Eu(III) cation is eightfold coordinated by four carboxyl­ate O atoms, one pyridine N atom, two MeOH and one chloride anion in the form of a distorted polyhedron. Extended coordination of the PDC ligand lead to the formation of a two-dimensional coordination polymer parallel to (10-1).
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spelling pubmed-33444022012-05-15 Poly[[chloridodimethanol(μ(3)-pyridine-2,3-dicarboxyl­ato)europium(III)] methanol monosolvate] Wu, Dayu Chen, Liyang Wu, Genhua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, {[Eu(C(7)H(3)NO(4))Cl(CH(3)OH)(2)]·CH(3)OH}(n), contains one Eu(III) ion, one pyridine 2,3-dicarboxylate dianion (PDC), two CH(3)OH mol­ecules coordinating to the metal atom, one coordinating chloride and one lattice occluded CH(3)OH mol­ecule. In the crystal, each PDC anion coordinates to three adjacent Eu(III) ions by the pyridine N and O atoms of the carboxyl­ate groups. The Eu(III) cation is eightfold coordinated by four carboxyl­ate O atoms, one pyridine N atom, two MeOH and one chloride anion in the form of a distorted polyhedron. Extended coordination of the PDC ligand lead to the formation of a two-dimensional coordination polymer parallel to (10-1). International Union of Crystallography 2012-04-28 /pmc/articles/PMC3344402/ /pubmed/22590164 http://dx.doi.org/10.1107/S1600536812017862 Text en © Wu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wu, Dayu
Chen, Liyang
Wu, Genhua
Poly[[chloridodimethanol(μ(3)-pyridine-2,3-dicarboxyl­ato)europium(III)] methanol monosolvate]
title Poly[[chloridodimethanol(μ(3)-pyridine-2,3-dicarboxyl­ato)europium(III)] methanol monosolvate]
title_full Poly[[chloridodimethanol(μ(3)-pyridine-2,3-dicarboxyl­ato)europium(III)] methanol monosolvate]
title_fullStr Poly[[chloridodimethanol(μ(3)-pyridine-2,3-dicarboxyl­ato)europium(III)] methanol monosolvate]
title_full_unstemmed Poly[[chloridodimethanol(μ(3)-pyridine-2,3-dicarboxyl­ato)europium(III)] methanol monosolvate]
title_short Poly[[chloridodimethanol(μ(3)-pyridine-2,3-dicarboxyl­ato)europium(III)] methanol monosolvate]
title_sort poly[[chloridodimethanol(μ(3)-pyridine-2,3-dicarboxyl­ato)europium(iii)] methanol monosolvate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344402/
https://www.ncbi.nlm.nih.gov/pubmed/22590164
http://dx.doi.org/10.1107/S1600536812017862
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