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Bis(2-aminobenzothiazol-3-ium) bis(7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato-κ(3) O (2),O (3),O (7))nickelate(II) hexahydrate
In the title compound, (C(7)H(7)N(2)S)(2)[Ni(C(8)H(8)O(5))(2)]·6H(2)O, the Ni(II) cation is located on an inversion center and is O,O′,O′′-chelated by two symmetry-related 7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylate anions in a distorted octahedral geometry. The 2-aminobenzothiazol-3-ium catio...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344403/ https://www.ncbi.nlm.nih.gov/pubmed/22590165 http://dx.doi.org/10.1107/S1600536812017722 |
| _version_ | 1782231983884075008 |
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| author | Wang, Gui-Xian Zhang, Qi-Wei Zhang, Fan |
| author_facet | Wang, Gui-Xian Zhang, Qi-Wei Zhang, Fan |
| author_sort | Wang, Gui-Xian |
| collection | PubMed |
| description | In the title compound, (C(7)H(7)N(2)S)(2)[Ni(C(8)H(8)O(5))(2)]·6H(2)O, the Ni(II) cation is located on an inversion center and is O,O′,O′′-chelated by two symmetry-related 7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylate anions in a distorted octahedral geometry. The 2-aminobenzothiazol-3-ium cation links with the Ni complex anion via N—H⋯O hydrogen bonding. Extensive O—H⋯O and N—H⋯O hydrogen bonds involving the lattice water molecules also occur in the crystal structure. |
| format | Online Article Text |
| id | pubmed-3344403 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33444032012-05-15 Bis(2-aminobenzothiazol-3-ium) bis(7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato-κ(3) O (2),O (3),O (7))nickelate(II) hexahydrate Wang, Gui-Xian Zhang, Qi-Wei Zhang, Fan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(7)H(7)N(2)S)(2)[Ni(C(8)H(8)O(5))(2)]·6H(2)O, the Ni(II) cation is located on an inversion center and is O,O′,O′′-chelated by two symmetry-related 7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylate anions in a distorted octahedral geometry. The 2-aminobenzothiazol-3-ium cation links with the Ni complex anion via N—H⋯O hydrogen bonding. Extensive O—H⋯O and N—H⋯O hydrogen bonds involving the lattice water molecules also occur in the crystal structure. International Union of Crystallography 2012-04-28 /pmc/articles/PMC3344403/ /pubmed/22590165 http://dx.doi.org/10.1107/S1600536812017722 Text en © Wang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wang, Gui-Xian Zhang, Qi-Wei Zhang, Fan Bis(2-aminobenzothiazol-3-ium) bis(7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato-κ(3) O (2),O (3),O (7))nickelate(II) hexahydrate |
| title | Bis(2-aminobenzothiazol-3-ium) bis(7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato-κ(3)
O
(2),O
(3),O
(7))nickelate(II) hexahydrate |
| title_full | Bis(2-aminobenzothiazol-3-ium) bis(7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato-κ(3)
O
(2),O
(3),O
(7))nickelate(II) hexahydrate |
| title_fullStr | Bis(2-aminobenzothiazol-3-ium) bis(7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato-κ(3)
O
(2),O
(3),O
(7))nickelate(II) hexahydrate |
| title_full_unstemmed | Bis(2-aminobenzothiazol-3-ium) bis(7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato-κ(3)
O
(2),O
(3),O
(7))nickelate(II) hexahydrate |
| title_short | Bis(2-aminobenzothiazol-3-ium) bis(7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato-κ(3)
O
(2),O
(3),O
(7))nickelate(II) hexahydrate |
| title_sort | bis(2-aminobenzothiazol-3-ium) bis(7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato-κ(3)
o
(2),o
(3),o
(7))nickelate(ii) hexahydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344403/ https://www.ncbi.nlm.nih.gov/pubmed/22590165 http://dx.doi.org/10.1107/S1600536812017722 |
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