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Bis(2-amino­benzothia­zol-3-ium) bis­(7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato-κ(3) O (2),O (3),O (7))zincate hexa­hydrate

In the title hydrated mol­ecular salt, (C(7)H(7)N(2)S)(2)[Zn(C(8)H(8)O(5))(2)]·6H(2)O, which is isotypic with its Mn(II), Co(II) and Ni(II) analogues, the Zn(2+) ion lies on a crystallographic inversion centre and a distorted ZnO(6) octa­hedral coordination geometry arises from the two doubly deprot...

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Detalles Bibliográficos
Autores principales: Zhang, Fan, Lv, Tian-Xi, Feng, Jie, Lin, Qiu-Yue
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344404/
https://www.ncbi.nlm.nih.gov/pubmed/22590166
http://dx.doi.org/10.1107/S1600536812017886
Descripción
Sumario:In the title hydrated mol­ecular salt, (C(7)H(7)N(2)S)(2)[Zn(C(8)H(8)O(5))(2)]·6H(2)O, which is isotypic with its Mn(II), Co(II) and Ni(II) analogues, the Zn(2+) ion lies on a crystallographic inversion centre and a distorted ZnO(6) octa­hedral coordination geometry arises from the two doubly deprotonated O,O′,O′′-tridentate ligands. In the crystal, the components are linked by N—H⋯O(a), N—H⋯O(w), O(w)—H⋯O(a) and O(w)—H⋯O(w) hydrogen bonds (w = water and a = anion).