trans-Diaqua­bis­(1H imidazolium-4,5-di­carboxyl­ato-κ(2) O (4),O (5))magnesium

The title compound, [Mg(C(5)H(3)N(2)O(4))(2)(H(2)O)(2)], consists of centrosymmetric neutral monomers in which two O,O′-bidentate imidazolinium-4,5-dicarboxyl­ate ligands are bonded to the Mg(II) ion. One of the carboxyl protons is transferred to the N atom of the imidazole ring. The octa­hedral met...

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Autores principales: Łuczyńska-Szymczak, Katarzyna, Starosta, Wojciech, Leciejewicz, Janusz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344407/
https://www.ncbi.nlm.nih.gov/pubmed/22590169
http://dx.doi.org/10.1107/S1600536812017667
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author Łuczyńska-Szymczak, Katarzyna
Starosta, Wojciech
Leciejewicz, Janusz
author_facet Łuczyńska-Szymczak, Katarzyna
Starosta, Wojciech
Leciejewicz, Janusz
author_sort Łuczyńska-Szymczak, Katarzyna
collection PubMed
description The title compound, [Mg(C(5)H(3)N(2)O(4))(2)(H(2)O)(2)], consists of centrosymmetric neutral monomers in which two O,O′-bidentate imidazolinium-4,5-dicarboxyl­ate ligands are bonded to the Mg(II) ion. One of the carboxyl protons is transferred to the N atom of the imidazole ring. The octa­hedral metal-ion coordination is completed by two trans water O atoms. In the crystal, mol­ecules are linked by N—H⋯(O,O) and O—H⋯O hydrogen bonds.
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spelling pubmed-33444072012-05-15 trans-Diaqua­bis­(1H imidazolium-4,5-di­carboxyl­ato-κ(2) O (4),O (5))magnesium Łuczyńska-Szymczak, Katarzyna Starosta, Wojciech Leciejewicz, Janusz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Mg(C(5)H(3)N(2)O(4))(2)(H(2)O)(2)], consists of centrosymmetric neutral monomers in which two O,O′-bidentate imidazolinium-4,5-dicarboxyl­ate ligands are bonded to the Mg(II) ion. One of the carboxyl protons is transferred to the N atom of the imidazole ring. The octa­hedral metal-ion coordination is completed by two trans water O atoms. In the crystal, mol­ecules are linked by N—H⋯(O,O) and O—H⋯O hydrogen bonds. International Union of Crystallography 2012-04-28 /pmc/articles/PMC3344407/ /pubmed/22590169 http://dx.doi.org/10.1107/S1600536812017667 Text en © Łuczyńska-Szymczak et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Łuczyńska-Szymczak, Katarzyna
Starosta, Wojciech
Leciejewicz, Janusz
trans-Diaqua­bis­(1H imidazolium-4,5-di­carboxyl­ato-κ(2) O (4),O (5))magnesium
title trans-Diaqua­bis­(1H imidazolium-4,5-di­carboxyl­ato-κ(2) O (4),O (5))magnesium
title_full trans-Diaqua­bis­(1H imidazolium-4,5-di­carboxyl­ato-κ(2) O (4),O (5))magnesium
title_fullStr trans-Diaqua­bis­(1H imidazolium-4,5-di­carboxyl­ato-κ(2) O (4),O (5))magnesium
title_full_unstemmed trans-Diaqua­bis­(1H imidazolium-4,5-di­carboxyl­ato-κ(2) O (4),O (5))magnesium
title_short trans-Diaqua­bis­(1H imidazolium-4,5-di­carboxyl­ato-κ(2) O (4),O (5))magnesium
title_sort trans-diaqua­bis­(1h imidazolium-4,5-di­carboxyl­ato-κ(2) o (4),o (5))magnesium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344407/
https://www.ncbi.nlm.nih.gov/pubmed/22590169
http://dx.doi.org/10.1107/S1600536812017667
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