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catena-Poly[[[diaquanickel(II)]-μ-pyrazine-2-carboxylato-silver(I)-μ-pyrazine-2-carboxylato] nitrate dihydrate]
In the polymeric complex of the title compound, {[AgNi(C(5)H(3)N(2)O(2))(2)(H(2)O)(2)]NO(3)·2H(2)O}(n), the Ag(I) ion displays an angular coordination geometry with two N atoms from pyrazine-2-carboxylate ligands, and the Ni(II) ion is hexacoordinated by two O atoms from two water molecules, two...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344408/ https://www.ncbi.nlm.nih.gov/pubmed/22590170 http://dx.doi.org/10.1107/S1600536812018119 |
Sumario: | In the polymeric complex of the title compound, {[AgNi(C(5)H(3)N(2)O(2))(2)(H(2)O)(2)]NO(3)·2H(2)O}(n), the Ag(I) ion displays an angular coordination geometry with two N atoms from pyrazine-2-carboxylate ligands, and the Ni(II) ion is hexacoordinated by two O atoms from two water molecules, two O and two N atoms from pyrazine-2-carboxylate ligands in a distorted octahedral geometry. In the crystal, the Ag(I) and Ni(II) ions lie on a mirror plane and an inversion centre, respectively. The complex chains, the nitrate ions and the uncoordinated water molecules are linked together through O—H⋯O hydrogen bonds and weak Ag⋯O interactions [2.619 (17)–2.749 (17) Å] into a three-dimensional network. |
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