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catena-Poly[[[diaqua­nickel(II)]-μ-pyrazine-2-carboxyl­ato-silver(I)-μ-pyrazine-2-carboxyl­ato] nitrate dihydrate]

In the polymeric complex of the title compound, {[AgNi(C(5)H(3)N(2)O(2))(2)(H(2)O)(2)]NO(3)·2H(2)O}(n), the Ag(I) ion displays an angular coordination geometry with two N atoms from pyrazine-2-carboxyl­ate ligands, and the Ni(II) ion is hexa­coordinated by two O atoms from two water mol­ecules, two...

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Detalles Bibliográficos
Autores principales: Yang, Min, Chai, Li-Yuan, Yi, Xiao-Yi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344408/
https://www.ncbi.nlm.nih.gov/pubmed/22590170
http://dx.doi.org/10.1107/S1600536812018119
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author Yang, Min
Chai, Li-Yuan
Yi, Xiao-Yi
author_facet Yang, Min
Chai, Li-Yuan
Yi, Xiao-Yi
author_sort Yang, Min
collection PubMed
description In the polymeric complex of the title compound, {[AgNi(C(5)H(3)N(2)O(2))(2)(H(2)O)(2)]NO(3)·2H(2)O}(n), the Ag(I) ion displays an angular coordination geometry with two N atoms from pyrazine-2-carboxyl­ate ligands, and the Ni(II) ion is hexa­coordinated by two O atoms from two water mol­ecules, two O and two N atoms from pyrazine-2-carboxyl­ate ligands in a distorted octa­hedral geometry. In the crystal, the Ag(I) and Ni(II) ions lie on a mirror plane and an inversion centre, respectively. The complex chains, the nitrate ions and the uncoordinated water mol­ecules are linked together through O—H⋯O hydrogen bonds and weak Ag⋯O inter­actions [2.619 (17)–2.749 (17) Å] into a three-dimensional network.
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spelling pubmed-33444082012-05-15 catena-Poly[[[diaqua­nickel(II)]-μ-pyrazine-2-carboxyl­ato-silver(I)-μ-pyrazine-2-carboxyl­ato] nitrate dihydrate] Yang, Min Chai, Li-Yuan Yi, Xiao-Yi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the polymeric complex of the title compound, {[AgNi(C(5)H(3)N(2)O(2))(2)(H(2)O)(2)]NO(3)·2H(2)O}(n), the Ag(I) ion displays an angular coordination geometry with two N atoms from pyrazine-2-carboxyl­ate ligands, and the Ni(II) ion is hexa­coordinated by two O atoms from two water mol­ecules, two O and two N atoms from pyrazine-2-carboxyl­ate ligands in a distorted octa­hedral geometry. In the crystal, the Ag(I) and Ni(II) ions lie on a mirror plane and an inversion centre, respectively. The complex chains, the nitrate ions and the uncoordinated water mol­ecules are linked together through O—H⋯O hydrogen bonds and weak Ag⋯O inter­actions [2.619 (17)–2.749 (17) Å] into a three-dimensional network. International Union of Crystallography 2012-04-28 /pmc/articles/PMC3344408/ /pubmed/22590170 http://dx.doi.org/10.1107/S1600536812018119 Text en © Yang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Min
Chai, Li-Yuan
Yi, Xiao-Yi
catena-Poly[[[diaqua­nickel(II)]-μ-pyrazine-2-carboxyl­ato-silver(I)-μ-pyrazine-2-carboxyl­ato] nitrate dihydrate]
title catena-Poly[[[diaqua­nickel(II)]-μ-pyrazine-2-carboxyl­ato-silver(I)-μ-pyrazine-2-carboxyl­ato] nitrate dihydrate]
title_full catena-Poly[[[diaqua­nickel(II)]-μ-pyrazine-2-carboxyl­ato-silver(I)-μ-pyrazine-2-carboxyl­ato] nitrate dihydrate]
title_fullStr catena-Poly[[[diaqua­nickel(II)]-μ-pyrazine-2-carboxyl­ato-silver(I)-μ-pyrazine-2-carboxyl­ato] nitrate dihydrate]
title_full_unstemmed catena-Poly[[[diaqua­nickel(II)]-μ-pyrazine-2-carboxyl­ato-silver(I)-μ-pyrazine-2-carboxyl­ato] nitrate dihydrate]
title_short catena-Poly[[[diaqua­nickel(II)]-μ-pyrazine-2-carboxyl­ato-silver(I)-μ-pyrazine-2-carboxyl­ato] nitrate dihydrate]
title_sort catena-poly[[[diaqua­nickel(ii)]-μ-pyrazine-2-carboxyl­ato-silver(i)-μ-pyrazine-2-carboxyl­ato] nitrate dihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344408/
https://www.ncbi.nlm.nih.gov/pubmed/22590170
http://dx.doi.org/10.1107/S1600536812018119
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