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catena-Poly[[[diaquanickel(II)]-μ-pyrazine-2-carboxylato-silver(I)-μ-pyrazine-2-carboxylato] nitrate dihydrate]
In the polymeric complex of the title compound, {[AgNi(C(5)H(3)N(2)O(2))(2)(H(2)O)(2)]NO(3)·2H(2)O}(n), the Ag(I) ion displays an angular coordination geometry with two N atoms from pyrazine-2-carboxylate ligands, and the Ni(II) ion is hexacoordinated by two O atoms from two water molecules, two...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344408/ https://www.ncbi.nlm.nih.gov/pubmed/22590170 http://dx.doi.org/10.1107/S1600536812018119 |
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author | Yang, Min Chai, Li-Yuan Yi, Xiao-Yi |
author_facet | Yang, Min Chai, Li-Yuan Yi, Xiao-Yi |
author_sort | Yang, Min |
collection | PubMed |
description | In the polymeric complex of the title compound, {[AgNi(C(5)H(3)N(2)O(2))(2)(H(2)O)(2)]NO(3)·2H(2)O}(n), the Ag(I) ion displays an angular coordination geometry with two N atoms from pyrazine-2-carboxylate ligands, and the Ni(II) ion is hexacoordinated by two O atoms from two water molecules, two O and two N atoms from pyrazine-2-carboxylate ligands in a distorted octahedral geometry. In the crystal, the Ag(I) and Ni(II) ions lie on a mirror plane and an inversion centre, respectively. The complex chains, the nitrate ions and the uncoordinated water molecules are linked together through O—H⋯O hydrogen bonds and weak Ag⋯O interactions [2.619 (17)–2.749 (17) Å] into a three-dimensional network. |
format | Online Article Text |
id | pubmed-3344408 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33444082012-05-15 catena-Poly[[[diaquanickel(II)]-μ-pyrazine-2-carboxylato-silver(I)-μ-pyrazine-2-carboxylato] nitrate dihydrate] Yang, Min Chai, Li-Yuan Yi, Xiao-Yi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the polymeric complex of the title compound, {[AgNi(C(5)H(3)N(2)O(2))(2)(H(2)O)(2)]NO(3)·2H(2)O}(n), the Ag(I) ion displays an angular coordination geometry with two N atoms from pyrazine-2-carboxylate ligands, and the Ni(II) ion is hexacoordinated by two O atoms from two water molecules, two O and two N atoms from pyrazine-2-carboxylate ligands in a distorted octahedral geometry. In the crystal, the Ag(I) and Ni(II) ions lie on a mirror plane and an inversion centre, respectively. The complex chains, the nitrate ions and the uncoordinated water molecules are linked together through O—H⋯O hydrogen bonds and weak Ag⋯O interactions [2.619 (17)–2.749 (17) Å] into a three-dimensional network. International Union of Crystallography 2012-04-28 /pmc/articles/PMC3344408/ /pubmed/22590170 http://dx.doi.org/10.1107/S1600536812018119 Text en © Yang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yang, Min Chai, Li-Yuan Yi, Xiao-Yi catena-Poly[[[diaquanickel(II)]-μ-pyrazine-2-carboxylato-silver(I)-μ-pyrazine-2-carboxylato] nitrate dihydrate] |
title |
catena-Poly[[[diaquanickel(II)]-μ-pyrazine-2-carboxylato-silver(I)-μ-pyrazine-2-carboxylato] nitrate dihydrate] |
title_full |
catena-Poly[[[diaquanickel(II)]-μ-pyrazine-2-carboxylato-silver(I)-μ-pyrazine-2-carboxylato] nitrate dihydrate] |
title_fullStr |
catena-Poly[[[diaquanickel(II)]-μ-pyrazine-2-carboxylato-silver(I)-μ-pyrazine-2-carboxylato] nitrate dihydrate] |
title_full_unstemmed |
catena-Poly[[[diaquanickel(II)]-μ-pyrazine-2-carboxylato-silver(I)-μ-pyrazine-2-carboxylato] nitrate dihydrate] |
title_short |
catena-Poly[[[diaquanickel(II)]-μ-pyrazine-2-carboxylato-silver(I)-μ-pyrazine-2-carboxylato] nitrate dihydrate] |
title_sort | catena-poly[[[diaquanickel(ii)]-μ-pyrazine-2-carboxylato-silver(i)-μ-pyrazine-2-carboxylato] nitrate dihydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344408/ https://www.ncbi.nlm.nih.gov/pubmed/22590170 http://dx.doi.org/10.1107/S1600536812018119 |
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