Di-μ-bromido-bis­{[N,N-dimethyl-N′-(thio­phen-2-yl­methyl­idene)ethane-1,2-diamine]­copper(I)]}

In the crystal structure of the title compound, [Cu(2)Br(2)(C(9)H(14)N(2)S)(2)], the mol­ecule resides about a crystallographic inversion center. The coordination sphere around each copper ion has a distorted tetra­hedral geometry, with ligation by two bridging bromide ions, an amine N atom and an i...

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Detalles Bibliográficos
Autores principales: Goh, Christopher, Remillard, Zachary D., Martinez, Andre P., Keeley, Amanda C., Jasinski, Jerry P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344410/
https://www.ncbi.nlm.nih.gov/pubmed/22590172
http://dx.doi.org/10.1107/S1600536812017989
Descripción
Sumario:In the crystal structure of the title compound, [Cu(2)Br(2)(C(9)H(14)N(2)S)(2)], the mol­ecule resides about a crystallographic inversion center. The coordination sphere around each copper ion has a distorted tetra­hedral geometry, with ligation by two bridging bromide ions, an amine N atom and an imine N atom. The thio­phene ring is disordered over two sites, with occupancies of 0.719 (3) and 0.281 (3). Weak C—H⋯π inter­actions feature in the crystal packing.

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