Di-μ-bromido-bis­{[N,N-dimethyl-N′-(thio­phen-2-yl­methyl­idene)ethane-1,2-diamine]­copper(I)]}

In the crystal structure of the title compound, [Cu(2)Br(2)(C(9)H(14)N(2)S)(2)], the mol­ecule resides about a crystallographic inversion center. The coordination sphere around each copper ion has a distorted tetra­hedral geometry, with ligation by two bridging bromide ions, an amine N atom and an i...

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Autores principales: Goh, Christopher, Remillard, Zachary D., Martinez, Andre P., Keeley, Amanda C., Jasinski, Jerry P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344410/
https://www.ncbi.nlm.nih.gov/pubmed/22590172
http://dx.doi.org/10.1107/S1600536812017989
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author Goh, Christopher
Remillard, Zachary D.
Martinez, Andre P.
Keeley, Amanda C.
Jasinski, Jerry P.
author_facet Goh, Christopher
Remillard, Zachary D.
Martinez, Andre P.
Keeley, Amanda C.
Jasinski, Jerry P.
author_sort Goh, Christopher
collection PubMed
description In the crystal structure of the title compound, [Cu(2)Br(2)(C(9)H(14)N(2)S)(2)], the mol­ecule resides about a crystallographic inversion center. The coordination sphere around each copper ion has a distorted tetra­hedral geometry, with ligation by two bridging bromide ions, an amine N atom and an imine N atom. The thio­phene ring is disordered over two sites, with occupancies of 0.719 (3) and 0.281 (3). Weak C—H⋯π inter­actions feature in the crystal packing.
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spelling pubmed-33444102012-05-15 Di-μ-bromido-bis­{[N,N-dimethyl-N′-(thio­phen-2-yl­methyl­idene)ethane-1,2-diamine]­copper(I)]} Goh, Christopher Remillard, Zachary D. Martinez, Andre P. Keeley, Amanda C. Jasinski, Jerry P. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Cu(2)Br(2)(C(9)H(14)N(2)S)(2)], the mol­ecule resides about a crystallographic inversion center. The coordination sphere around each copper ion has a distorted tetra­hedral geometry, with ligation by two bridging bromide ions, an amine N atom and an imine N atom. The thio­phene ring is disordered over two sites, with occupancies of 0.719 (3) and 0.281 (3). Weak C—H⋯π inter­actions feature in the crystal packing. International Union of Crystallography 2012-04-28 /pmc/articles/PMC3344410/ /pubmed/22590172 http://dx.doi.org/10.1107/S1600536812017989 Text en © Goh et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Goh, Christopher
Remillard, Zachary D.
Martinez, Andre P.
Keeley, Amanda C.
Jasinski, Jerry P.
Di-μ-bromido-bis­{[N,N-dimethyl-N′-(thio­phen-2-yl­methyl­idene)ethane-1,2-diamine]­copper(I)]}
title Di-μ-bromido-bis­{[N,N-dimethyl-N′-(thio­phen-2-yl­methyl­idene)ethane-1,2-diamine]­copper(I)]}
title_full Di-μ-bromido-bis­{[N,N-dimethyl-N′-(thio­phen-2-yl­methyl­idene)ethane-1,2-diamine]­copper(I)]}
title_fullStr Di-μ-bromido-bis­{[N,N-dimethyl-N′-(thio­phen-2-yl­methyl­idene)ethane-1,2-diamine]­copper(I)]}
title_full_unstemmed Di-μ-bromido-bis­{[N,N-dimethyl-N′-(thio­phen-2-yl­methyl­idene)ethane-1,2-diamine]­copper(I)]}
title_short Di-μ-bromido-bis­{[N,N-dimethyl-N′-(thio­phen-2-yl­methyl­idene)ethane-1,2-diamine]­copper(I)]}
title_sort di-μ-bromido-bis­{[n,n-dimethyl-n′-(thio­phen-2-yl­methyl­idene)ethane-1,2-diamine]­copper(i)]}
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344410/
https://www.ncbi.nlm.nih.gov/pubmed/22590172
http://dx.doi.org/10.1107/S1600536812017989
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