Chlorido[N,N′-dibenzyl-N,N′-bis­(pyridin-2-ylmeth­yl)ethane-1,2-diamine]­copper(II) perchlorate methanol monosolvate

In the title solvated mol­ecular salt, [CuCl(C(28)H(30)N(4))]ClO(4)·CH(3)OH, the Cu(2+) ion is coordinated by the N,N′,N′′,N′′′-tetra­dentate ligand and a chloride ion, generating a very distorted square-based pyramidal CuN(4)Cl coordination geometry with the Cl(−) ion in the basal position. In the...

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Detalles Bibliográficos
Autores principales: Song, Hui-Ting, Mao, Jia-Wei, Liu, Ming, Pan, Zhi-Quan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344412/
https://www.ncbi.nlm.nih.gov/pubmed/22590174
http://dx.doi.org/10.1107/S1600536812017941
Descripción
Sumario:In the title solvated mol­ecular salt, [CuCl(C(28)H(30)N(4))]ClO(4)·CH(3)OH, the Cu(2+) ion is coordinated by the N,N′,N′′,N′′′-tetra­dentate ligand and a chloride ion, generating a very distorted square-based pyramidal CuN(4)Cl coordination geometry with the Cl(−) ion in the basal position. In the crystal, the solvent mol­ecules and anions are linked by weak O—H⋯O hydrogen bonding.

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