Chlorido[N,N′-dibenzyl-N,N′-bis­(pyridin-2-ylmeth­yl)ethane-1,2-diamine]­copper(II) perchlorate methanol monosolvate

In the title solvated mol­ecular salt, [CuCl(C(28)H(30)N(4))]ClO(4)·CH(3)OH, the Cu(2+) ion is coordinated by the N,N′,N′′,N′′′-tetra­dentate ligand and a chloride ion, generating a very distorted square-based pyramidal CuN(4)Cl coordination geometry with the Cl(−) ion in the basal position. In the...

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Detalles Bibliográficos
Autores principales: Song, Hui-Ting, Mao, Jia-Wei, Liu, Ming, Pan, Zhi-Quan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344412/
https://www.ncbi.nlm.nih.gov/pubmed/22590174
http://dx.doi.org/10.1107/S1600536812017941
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author Song, Hui-Ting
Mao, Jia-Wei
Liu, Ming
Pan, Zhi-Quan
author_facet Song, Hui-Ting
Mao, Jia-Wei
Liu, Ming
Pan, Zhi-Quan
author_sort Song, Hui-Ting
collection PubMed
description In the title solvated mol­ecular salt, [CuCl(C(28)H(30)N(4))]ClO(4)·CH(3)OH, the Cu(2+) ion is coordinated by the N,N′,N′′,N′′′-tetra­dentate ligand and a chloride ion, generating a very distorted square-based pyramidal CuN(4)Cl coordination geometry with the Cl(−) ion in the basal position. In the crystal, the solvent mol­ecules and anions are linked by weak O—H⋯O hydrogen bonding.
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spelling pubmed-33444122012-05-15 Chlorido[N,N′-dibenzyl-N,N′-bis­(pyridin-2-ylmeth­yl)ethane-1,2-diamine]­copper(II) perchlorate methanol monosolvate Song, Hui-Ting Mao, Jia-Wei Liu, Ming Pan, Zhi-Quan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title solvated mol­ecular salt, [CuCl(C(28)H(30)N(4))]ClO(4)·CH(3)OH, the Cu(2+) ion is coordinated by the N,N′,N′′,N′′′-tetra­dentate ligand and a chloride ion, generating a very distorted square-based pyramidal CuN(4)Cl coordination geometry with the Cl(−) ion in the basal position. In the crystal, the solvent mol­ecules and anions are linked by weak O—H⋯O hydrogen bonding. International Union of Crystallography 2012-04-28 /pmc/articles/PMC3344412/ /pubmed/22590174 http://dx.doi.org/10.1107/S1600536812017941 Text en © Song et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Song, Hui-Ting
Mao, Jia-Wei
Liu, Ming
Pan, Zhi-Quan
Chlorido[N,N′-dibenzyl-N,N′-bis­(pyridin-2-ylmeth­yl)ethane-1,2-diamine]­copper(II) perchlorate methanol monosolvate
title Chlorido[N,N′-dibenzyl-N,N′-bis­(pyridin-2-ylmeth­yl)ethane-1,2-diamine]­copper(II) perchlorate methanol monosolvate
title_full Chlorido[N,N′-dibenzyl-N,N′-bis­(pyridin-2-ylmeth­yl)ethane-1,2-diamine]­copper(II) perchlorate methanol monosolvate
title_fullStr Chlorido[N,N′-dibenzyl-N,N′-bis­(pyridin-2-ylmeth­yl)ethane-1,2-diamine]­copper(II) perchlorate methanol monosolvate
title_full_unstemmed Chlorido[N,N′-dibenzyl-N,N′-bis­(pyridin-2-ylmeth­yl)ethane-1,2-diamine]­copper(II) perchlorate methanol monosolvate
title_short Chlorido[N,N′-dibenzyl-N,N′-bis­(pyridin-2-ylmeth­yl)ethane-1,2-diamine]­copper(II) perchlorate methanol monosolvate
title_sort chlorido[n,n′-dibenzyl-n,n′-bis­(pyridin-2-ylmeth­yl)ethane-1,2-diamine]­copper(ii) perchlorate methanol monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344412/
https://www.ncbi.nlm.nih.gov/pubmed/22590174
http://dx.doi.org/10.1107/S1600536812017941
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