Hexa­kis­(dimethyl sulfoxide-κO)calcium μ(6)-oxido-dodeca­kis-μ(2)-oxido-hexa­oxido­hexa­tungstate(VI)

In the title compound, [Ca(C(2)H(6)OS)(6)][W(6)O(19)], the cation and anion both have a crystallographically imposed centre of symmetry. The Ca(II) atom in the cation is coordinated by six O atoms from six dimethyl sulfoxide ligands in a distorted octa­hedral geometry. The [W(6)O(19)](2−) isopolyani...

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Autor principal: Zhang, Jinfang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344417/
https://www.ncbi.nlm.nih.gov/pubmed/22590179
http://dx.doi.org/10.1107/S1600536812018338
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author Zhang, Jinfang
author_facet Zhang, Jinfang
author_sort Zhang, Jinfang
collection PubMed
description In the title compound, [Ca(C(2)H(6)OS)(6)][W(6)O(19)], the cation and anion both have a crystallographically imposed centre of symmetry. The Ca(II) atom in the cation is coordinated by six O atoms from six dimethyl sulfoxide ligands in a distorted octa­hedral geometry. The [W(6)O(19)](2−) isopolyanion possesses the well-known Lindqvist structure in which each W(VI) atom is coordinated by four μ(2)-O, one terminal O and one μ(6)-O atom.
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spelling pubmed-33444172012-05-15 Hexa­kis­(dimethyl sulfoxide-κO)calcium μ(6)-oxido-dodeca­kis-μ(2)-oxido-hexa­oxido­hexa­tungstate(VI) Zhang, Jinfang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ca(C(2)H(6)OS)(6)][W(6)O(19)], the cation and anion both have a crystallographically imposed centre of symmetry. The Ca(II) atom in the cation is coordinated by six O atoms from six dimethyl sulfoxide ligands in a distorted octa­hedral geometry. The [W(6)O(19)](2−) isopolyanion possesses the well-known Lindqvist structure in which each W(VI) atom is coordinated by four μ(2)-O, one terminal O and one μ(6)-O atom. International Union of Crystallography 2012-04-28 /pmc/articles/PMC3344417/ /pubmed/22590179 http://dx.doi.org/10.1107/S1600536812018338 Text en © Jinfang Zhang 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Jinfang
Hexa­kis­(dimethyl sulfoxide-κO)calcium μ(6)-oxido-dodeca­kis-μ(2)-oxido-hexa­oxido­hexa­tungstate(VI)
title Hexa­kis­(dimethyl sulfoxide-κO)calcium μ(6)-oxido-dodeca­kis-μ(2)-oxido-hexa­oxido­hexa­tungstate(VI)
title_full Hexa­kis­(dimethyl sulfoxide-κO)calcium μ(6)-oxido-dodeca­kis-μ(2)-oxido-hexa­oxido­hexa­tungstate(VI)
title_fullStr Hexa­kis­(dimethyl sulfoxide-κO)calcium μ(6)-oxido-dodeca­kis-μ(2)-oxido-hexa­oxido­hexa­tungstate(VI)
title_full_unstemmed Hexa­kis­(dimethyl sulfoxide-κO)calcium μ(6)-oxido-dodeca­kis-μ(2)-oxido-hexa­oxido­hexa­tungstate(VI)
title_short Hexa­kis­(dimethyl sulfoxide-κO)calcium μ(6)-oxido-dodeca­kis-μ(2)-oxido-hexa­oxido­hexa­tungstate(VI)
title_sort hexa­kis­(dimethyl sulfoxide-κo)calcium μ(6)-oxido-dodeca­kis-μ(2)-oxido-hexa­oxido­hexa­tungstate(vi)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344417/
https://www.ncbi.nlm.nih.gov/pubmed/22590179
http://dx.doi.org/10.1107/S1600536812018338
work_keys_str_mv AT zhangjinfang hexakisdimethylsulfoxidekocalciumm6oxidododecakism2oxidohexaoxidohexatungstatevi

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