Tetra­kis(triphenyl­phosphane-κP)silver(I) tetra­fluorido­borate

The title complex, [Ag(C(18)H(15)P)(4)]BF(4), was prepared by the reaction of silver(I) tetra­fluorido­borate and triphenyl­phosphane in the presence of 1,2-bis­(pyridin-2-yl)ethyl­ene. The Ag(I) atom is tetra­hedrally coordinated by four P atoms from triphenyl­phosphane (PPh(3)) ligands. Due to sym...

Descripción completa

Detalles Bibliográficos
Autores principales: Huang, Xu, Qiu, Qi-Ming, Wang, Xin, Jin, Qiong-Hua, Zhang, Cun-Lin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344421/
https://www.ncbi.nlm.nih.gov/pubmed/22590183
http://dx.doi.org/10.1107/S1600536812018247
Descripción
Sumario:The title complex, [Ag(C(18)H(15)P)(4)]BF(4), was prepared by the reaction of silver(I) tetra­fluorido­borate and triphenyl­phosphane in the presence of 1,2-bis­(pyridin-2-yl)ethyl­ene. The Ag(I) atom is tetra­hedrally coordinated by four P atoms from triphenyl­phosphane (PPh(3)) ligands. Due to symmetry, the tetra­fluorido­borate anion is disordered over three positions (each with one third occupancy). The tetra­fluorido­borate anion does not coordinate to the Ag(I) atom.

Ejemplares similares