Tetra­kis(triphenyl­phosphane-κP)silver(I) tetra­fluorido­borate

The title complex, [Ag(C(18)H(15)P)(4)]BF(4), was prepared by the reaction of silver(I) tetra­fluorido­borate and triphenyl­phosphane in the presence of 1,2-bis­(pyridin-2-yl)ethyl­ene. The Ag(I) atom is tetra­hedrally coordinated by four P atoms from triphenyl­phosphane (PPh(3)) ligands. Due to sym...

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Detalles Bibliográficos
Autores principales: Huang, Xu, Qiu, Qi-Ming, Wang, Xin, Jin, Qiong-Hua, Zhang, Cun-Lin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344421/
https://www.ncbi.nlm.nih.gov/pubmed/22590183
http://dx.doi.org/10.1107/S1600536812018247
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author Huang, Xu
Qiu, Qi-Ming
Wang, Xin
Jin, Qiong-Hua
Zhang, Cun-Lin
author_facet Huang, Xu
Qiu, Qi-Ming
Wang, Xin
Jin, Qiong-Hua
Zhang, Cun-Lin
author_sort Huang, Xu
collection PubMed
description The title complex, [Ag(C(18)H(15)P)(4)]BF(4), was prepared by the reaction of silver(I) tetra­fluorido­borate and triphenyl­phosphane in the presence of 1,2-bis­(pyridin-2-yl)ethyl­ene. The Ag(I) atom is tetra­hedrally coordinated by four P atoms from triphenyl­phosphane (PPh(3)) ligands. Due to symmetry, the tetra­fluorido­borate anion is disordered over three positions (each with one third occupancy). The tetra­fluorido­borate anion does not coordinate to the Ag(I) atom.
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spelling pubmed-33444212012-05-15 Tetra­kis(triphenyl­phosphane-κP)silver(I) tetra­fluorido­borate Huang, Xu Qiu, Qi-Ming Wang, Xin Jin, Qiong-Hua Zhang, Cun-Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Ag(C(18)H(15)P)(4)]BF(4), was prepared by the reaction of silver(I) tetra­fluorido­borate and triphenyl­phosphane in the presence of 1,2-bis­(pyridin-2-yl)ethyl­ene. The Ag(I) atom is tetra­hedrally coordinated by four P atoms from triphenyl­phosphane (PPh(3)) ligands. Due to symmetry, the tetra­fluorido­borate anion is disordered over three positions (each with one third occupancy). The tetra­fluorido­borate anion does not coordinate to the Ag(I) atom. International Union of Crystallography 2012-04-28 /pmc/articles/PMC3344421/ /pubmed/22590183 http://dx.doi.org/10.1107/S1600536812018247 Text en © Huang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Huang, Xu
Qiu, Qi-Ming
Wang, Xin
Jin, Qiong-Hua
Zhang, Cun-Lin
Tetra­kis(triphenyl­phosphane-κP)silver(I) tetra­fluorido­borate
title Tetra­kis(triphenyl­phosphane-κP)silver(I) tetra­fluorido­borate
title_full Tetra­kis(triphenyl­phosphane-κP)silver(I) tetra­fluorido­borate
title_fullStr Tetra­kis(triphenyl­phosphane-κP)silver(I) tetra­fluorido­borate
title_full_unstemmed Tetra­kis(triphenyl­phosphane-κP)silver(I) tetra­fluorido­borate
title_short Tetra­kis(triphenyl­phosphane-κP)silver(I) tetra­fluorido­borate
title_sort tetra­kis(triphenyl­phosphane-κp)silver(i) tetra­fluorido­borate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344421/
https://www.ncbi.nlm.nih.gov/pubmed/22590183
http://dx.doi.org/10.1107/S1600536812018247
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AT jinqionghua tetrakistriphenylphosphanekpsilveritetrafluoridoborate
AT zhangcunlin tetrakistriphenylphosphanekpsilveritetrafluoridoborate

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