Poly[di-μ(3)-acetato-μ(8)-(naphthalene-1,5-disulfonato)-dilead(II)]

In the polymeric title complex, [Pb(2)(CH(3)CO(2))(2)(C(10)H(6)O(6)S(2))](n), the acetate anion functions in a chelating mode and both O atoms also coordinate to adjacent Pb(II) atoms. The naphthalene-1,5-disulfonate dianion, which lies on a center of inversion, is connected to four Pb(II) atoms. Th...

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Detalles Bibliográficos
Autores principales: Gao, Shan, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344422/
https://www.ncbi.nlm.nih.gov/pubmed/22590184
http://dx.doi.org/10.1107/S160053681201834X
Descripción
Sumario:In the polymeric title complex, [Pb(2)(CH(3)CO(2))(2)(C(10)H(6)O(6)S(2))](n), the acetate anion functions in a chelating mode and both O atoms also coordinate to adjacent Pb(II) atoms. The naphthalene-1,5-disulfonate dianion, which lies on a center of inversion, is connected to four Pb(II) atoms. The bridging modes of the monoanion and dianion give rise to a three-dimensional coordination polymer. The Pb(II) atom is eight-coordinate in the form of an undefined coordination polyhedron.

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