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Poly[di-μ(3)-acetato-μ(8)-(naphthalene-1,5-disulfonato)-dilead(II)]
In the polymeric title complex, [Pb(2)(CH(3)CO(2))(2)(C(10)H(6)O(6)S(2))](n), the acetate anion functions in a chelating mode and both O atoms also coordinate to adjacent Pb(II) atoms. The naphthalene-1,5-disulfonate dianion, which lies on a center of inversion, is connected to four Pb(II) atoms. Th...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344422/ https://www.ncbi.nlm.nih.gov/pubmed/22590184 http://dx.doi.org/10.1107/S160053681201834X |
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author | Gao, Shan Ng, Seik Weng |
author_facet | Gao, Shan Ng, Seik Weng |
author_sort | Gao, Shan |
collection | PubMed |
description | In the polymeric title complex, [Pb(2)(CH(3)CO(2))(2)(C(10)H(6)O(6)S(2))](n), the acetate anion functions in a chelating mode and both O atoms also coordinate to adjacent Pb(II) atoms. The naphthalene-1,5-disulfonate dianion, which lies on a center of inversion, is connected to four Pb(II) atoms. The bridging modes of the monoanion and dianion give rise to a three-dimensional coordination polymer. The Pb(II) atom is eight-coordinate in the form of an undefined coordination polyhedron. |
format | Online Article Text |
id | pubmed-3344422 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33444222012-05-15 Poly[di-μ(3)-acetato-μ(8)-(naphthalene-1,5-disulfonato)-dilead(II)] Gao, Shan Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the polymeric title complex, [Pb(2)(CH(3)CO(2))(2)(C(10)H(6)O(6)S(2))](n), the acetate anion functions in a chelating mode and both O atoms also coordinate to adjacent Pb(II) atoms. The naphthalene-1,5-disulfonate dianion, which lies on a center of inversion, is connected to four Pb(II) atoms. The bridging modes of the monoanion and dianion give rise to a three-dimensional coordination polymer. The Pb(II) atom is eight-coordinate in the form of an undefined coordination polyhedron. International Union of Crystallography 2012-04-28 /pmc/articles/PMC3344422/ /pubmed/22590184 http://dx.doi.org/10.1107/S160053681201834X Text en © Gao and Ng 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Gao, Shan Ng, Seik Weng Poly[di-μ(3)-acetato-μ(8)-(naphthalene-1,5-disulfonato)-dilead(II)] |
title | Poly[di-μ(3)-acetato-μ(8)-(naphthalene-1,5-disulfonato)-dilead(II)] |
title_full | Poly[di-μ(3)-acetato-μ(8)-(naphthalene-1,5-disulfonato)-dilead(II)] |
title_fullStr | Poly[di-μ(3)-acetato-μ(8)-(naphthalene-1,5-disulfonato)-dilead(II)] |
title_full_unstemmed | Poly[di-μ(3)-acetato-μ(8)-(naphthalene-1,5-disulfonato)-dilead(II)] |
title_short | Poly[di-μ(3)-acetato-μ(8)-(naphthalene-1,5-disulfonato)-dilead(II)] |
title_sort | poly[di-μ(3)-acetato-μ(8)-(naphthalene-1,5-disulfonato)-dilead(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344422/ https://www.ncbi.nlm.nih.gov/pubmed/22590184 http://dx.doi.org/10.1107/S160053681201834X |
work_keys_str_mv | AT gaoshan polydim3acetatom8naphthalene15disulfonatodileadii AT ngseikweng polydim3acetatom8naphthalene15disulfonatodileadii |