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Dichloridobis[2-(1-hydrazinylideneeth­yl)pyrazine-κN (1)]zinc

In the structure of the title complex, [ZnCl(2)(C(6)H(8)N(4))(2)], the Zn(II) atom has a distorted octa­hedral geometry. Two cis Cl(−) ions and four N atoms belonging to two different 2-(1-hydrazinylideneeth­yl)pyrazine ligands coordinate the Zn(II) atom, forming two five-membered Zn—N—C—C—N rings....

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Detalles Bibliográficos
Autores principales: Liang, Li-li, Li, Meng, Liu, Jia-cheng, Wei, Yun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344425/
https://www.ncbi.nlm.nih.gov/pubmed/22590187
http://dx.doi.org/10.1107/S1600536812016418
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author Liang, Li-li
Li, Meng
Liu, Jia-cheng
Wei, Yun
author_facet Liang, Li-li
Li, Meng
Liu, Jia-cheng
Wei, Yun
author_sort Liang, Li-li
collection PubMed
description In the structure of the title complex, [ZnCl(2)(C(6)H(8)N(4))(2)], the Zn(II) atom has a distorted octa­hedral geometry. Two cis Cl(−) ions and four N atoms belonging to two different 2-(1-hydrazinylideneeth­yl)pyrazine ligands coordinate the Zn(II) atom, forming two five-membered Zn—N—C—C—N rings. The dihedral angle between the planes of these metallocycles is 88.13 (4)°. The organic ligands are essentially planar (r.m.s. deviations from planarity = 0.072 and 0.040 Å). Inter­molecular N—H⋯N and N—H⋯Cl inter­actions join the mol­ecules into a three-dimensional framework.
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spelling pubmed-33444252012-05-15 Dichloridobis[2-(1-hydrazinylideneeth­yl)pyrazine-κN (1)]zinc Liang, Li-li Li, Meng Liu, Jia-cheng Wei, Yun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title complex, [ZnCl(2)(C(6)H(8)N(4))(2)], the Zn(II) atom has a distorted octa­hedral geometry. Two cis Cl(−) ions and four N atoms belonging to two different 2-(1-hydrazinylideneeth­yl)pyrazine ligands coordinate the Zn(II) atom, forming two five-membered Zn—N—C—C—N rings. The dihedral angle between the planes of these metallocycles is 88.13 (4)°. The organic ligands are essentially planar (r.m.s. deviations from planarity = 0.072 and 0.040 Å). Inter­molecular N—H⋯N and N—H⋯Cl inter­actions join the mol­ecules into a three-dimensional framework. International Union of Crystallography 2012-04-28 /pmc/articles/PMC3344425/ /pubmed/22590187 http://dx.doi.org/10.1107/S1600536812016418 Text en © Liang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liang, Li-li
Li, Meng
Liu, Jia-cheng
Wei, Yun
Dichloridobis[2-(1-hydrazinylideneeth­yl)pyrazine-κN (1)]zinc
title Dichloridobis[2-(1-hydrazinylideneeth­yl)pyrazine-κN (1)]zinc
title_full Dichloridobis[2-(1-hydrazinylideneeth­yl)pyrazine-κN (1)]zinc
title_fullStr Dichloridobis[2-(1-hydrazinylideneeth­yl)pyrazine-κN (1)]zinc
title_full_unstemmed Dichloridobis[2-(1-hydrazinylideneeth­yl)pyrazine-κN (1)]zinc
title_short Dichloridobis[2-(1-hydrazinylideneeth­yl)pyrazine-κN (1)]zinc
title_sort dichloridobis[2-(1-hydrazinylideneeth­yl)pyrazine-κn (1)]zinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344425/
https://www.ncbi.nlm.nih.gov/pubmed/22590187
http://dx.doi.org/10.1107/S1600536812016418
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