(E)-Methyl 2-benzyl-3-o-tolyl­acrylate

In the title compound, C(18)H(18)O(2), the methyl acrylate substituent adopts an extended E conformation with all torsion angles close to 180°. The mean plane of the acrylate unit and the phenyl ring are approximately orthogonal to each other, making a dihedral angle of 81.40 (6)°. The position of t...

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Detalles Bibliográficos
Autores principales: Karthikeyan, S., Sethusankar, K., Devaraj, Anthonisamy, Bakthadoss, Manickam
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344426/
https://www.ncbi.nlm.nih.gov/pubmed/22590188
http://dx.doi.org/10.1107/S1600536812013438
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author Karthikeyan, S.
Sethusankar, K.
Devaraj, Anthonisamy
Bakthadoss, Manickam
author_facet Karthikeyan, S.
Sethusankar, K.
Devaraj, Anthonisamy
Bakthadoss, Manickam
author_sort Karthikeyan, S.
collection PubMed
description In the title compound, C(18)H(18)O(2), the methyl acrylate substituent adopts an extended E conformation with all torsion angles close to 180°. The mean plane of the acrylate unit and the phenyl ring are approximately orthogonal to each other, making a dihedral angle of 81.40 (6)°. The position of the carbonyl group with respect to the olefinic double bond is typically S-trans. The crystal packing is stabilized by inter­molecular C—H⋯π inter­actions.
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spelling pubmed-33444262012-05-15 (E)-Methyl 2-benzyl-3-o-tolyl­acrylate Karthikeyan, S. Sethusankar, K. Devaraj, Anthonisamy Bakthadoss, Manickam Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(18)O(2), the methyl acrylate substituent adopts an extended E conformation with all torsion angles close to 180°. The mean plane of the acrylate unit and the phenyl ring are approximately orthogonal to each other, making a dihedral angle of 81.40 (6)°. The position of the carbonyl group with respect to the olefinic double bond is typically S-trans. The crystal packing is stabilized by inter­molecular C—H⋯π inter­actions. International Union of Crystallography 2012-04-04 /pmc/articles/PMC3344426/ /pubmed/22590188 http://dx.doi.org/10.1107/S1600536812013438 Text en © Karthikeyan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Karthikeyan, S.
Sethusankar, K.
Devaraj, Anthonisamy
Bakthadoss, Manickam
(E)-Methyl 2-benzyl-3-o-tolyl­acrylate
title (E)-Methyl 2-benzyl-3-o-tolyl­acrylate
title_full (E)-Methyl 2-benzyl-3-o-tolyl­acrylate
title_fullStr (E)-Methyl 2-benzyl-3-o-tolyl­acrylate
title_full_unstemmed (E)-Methyl 2-benzyl-3-o-tolyl­acrylate
title_short (E)-Methyl 2-benzyl-3-o-tolyl­acrylate
title_sort (e)-methyl 2-benzyl-3-o-tolyl­acrylate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344426/
https://www.ncbi.nlm.nih.gov/pubmed/22590188
http://dx.doi.org/10.1107/S1600536812013438
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AT sethusankark emethyl2benzyl3otolylacrylate
AT devarajanthonisamy emethyl2benzyl3otolylacrylate
AT bakthadossmanickam emethyl2benzyl3otolylacrylate

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