5-(Thio­phen-2-ylmeth­yl)-1,3,4-thia­diazol-2-amine

In the title mol­ecule, C(7)H(7)N(3)S(2), the dihedral angle between the thio­phene and thia­diazole rings is 72.99 (5)°; the two rings are oriented so that the S atoms in each ring are on the same side. In the crystal, the three-dimensional network involves strong N—H⋯O hydrogen bonds, as well as C...

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Autores principales: Köysal, Yavuz, Deniz, Sadık, Butcher, Ray J., Öztürk Yildirim, Sema, Jasinski, Jerry P., Keeley, Amanda C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344432/
https://www.ncbi.nlm.nih.gov/pubmed/22590194
http://dx.doi.org/10.1107/S1600536812013633
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author Köysal, Yavuz
Deniz, Sadık
Butcher, Ray J.
Öztürk Yildirim, Sema
Jasinski, Jerry P.
Keeley, Amanda C.
author_facet Köysal, Yavuz
Deniz, Sadık
Butcher, Ray J.
Öztürk Yildirim, Sema
Jasinski, Jerry P.
Keeley, Amanda C.
author_sort Köysal, Yavuz
collection PubMed
description In the title mol­ecule, C(7)H(7)N(3)S(2), the dihedral angle between the thio­phene and thia­diazole rings is 72.99 (5)°; the two rings are oriented so that the S atoms in each ring are on the same side. In the crystal, the three-dimensional network involves strong N—H⋯O hydrogen bonds, as well as C—H⋯π and π–π stacking inter­actions [centroid–centroid distances = 3.654 (1) and 3.495 (1) Å].
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spelling pubmed-33444322012-05-15 5-(Thio­phen-2-ylmeth­yl)-1,3,4-thia­diazol-2-amine Köysal, Yavuz Deniz, Sadık Butcher, Ray J. Öztürk Yildirim, Sema Jasinski, Jerry P. Keeley, Amanda C. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(7)H(7)N(3)S(2), the dihedral angle between the thio­phene and thia­diazole rings is 72.99 (5)°; the two rings are oriented so that the S atoms in each ring are on the same side. In the crystal, the three-dimensional network involves strong N—H⋯O hydrogen bonds, as well as C—H⋯π and π–π stacking inter­actions [centroid–centroid distances = 3.654 (1) and 3.495 (1) Å]. International Union of Crystallography 2012-04-04 /pmc/articles/PMC3344432/ /pubmed/22590194 http://dx.doi.org/10.1107/S1600536812013633 Text en © Köysal et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Köysal, Yavuz
Deniz, Sadık
Butcher, Ray J.
Öztürk Yildirim, Sema
Jasinski, Jerry P.
Keeley, Amanda C.
5-(Thio­phen-2-ylmeth­yl)-1,3,4-thia­diazol-2-amine
title 5-(Thio­phen-2-ylmeth­yl)-1,3,4-thia­diazol-2-amine
title_full 5-(Thio­phen-2-ylmeth­yl)-1,3,4-thia­diazol-2-amine
title_fullStr 5-(Thio­phen-2-ylmeth­yl)-1,3,4-thia­diazol-2-amine
title_full_unstemmed 5-(Thio­phen-2-ylmeth­yl)-1,3,4-thia­diazol-2-amine
title_short 5-(Thio­phen-2-ylmeth­yl)-1,3,4-thia­diazol-2-amine
title_sort 5-(thio­phen-2-ylmeth­yl)-1,3,4-thia­diazol-2-amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344432/
https://www.ncbi.nlm.nih.gov/pubmed/22590194
http://dx.doi.org/10.1107/S1600536812013633
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