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Creatininium 2-chloroacetate
In the title compound (systematic name: 2-amino-1-methyl-4-oxo-4,5-dihydro-1H-imidazol-3-ium 2-chloroacetate), C(4)H(8)N(3)O(+)·C(2)H(2)ClO(2) (−), the molecular aggregations are stabilized through classical (N—H⋯O) and non-classical (C—H⋯O and C—H⋯N) hydrogen-bonding interactions. The cations a...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344436/ https://www.ncbi.nlm.nih.gov/pubmed/22590198 http://dx.doi.org/10.1107/S1600536812012068 |
Sumario: | In the title compound (systematic name: 2-amino-1-methyl-4-oxo-4,5-dihydro-1H-imidazol-3-ium 2-chloroacetate), C(4)H(8)N(3)O(+)·C(2)H(2)ClO(2) (−), the molecular aggregations are stabilized through classical (N—H⋯O) and non-classical (C—H⋯O and C—H⋯N) hydrogen-bonding interactions. The cations are linked to the anions, forming ion pairs through two N—H⋯O bonds that produce characteristic R (2) (2)(8) ring motifs. These cation–anion pairs are connected through another N—H⋯O hydrogen bond, leading to an R (4) (2)(8) ring motif. Further weak C—H⋯N interactions link the molecules along the a axis, while other C—H⋯O interactions generate zigzag chains extending along b. |
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