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N-(2,4-Dimethylphenyl)-2,2-diphenylacetamide
The asymmetric unit of the title compound, C(22)H(21)NO, consists of two crystallographically independent molecules (A and B). Each molecule contains two benzene rings and one dimethylbenzene ring. The dihedral angle between the two benzene rings is 87.75 (16)° in molecule A and 89.25 (16)° in m...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344457/ https://www.ncbi.nlm.nih.gov/pubmed/22590219 http://dx.doi.org/10.1107/S1600536812014079 |
Sumario: | The asymmetric unit of the title compound, C(22)H(21)NO, consists of two crystallographically independent molecules (A and B). Each molecule contains two benzene rings and one dimethylbenzene ring. The dihedral angle between the two benzene rings is 87.75 (16)° in molecule A and 89.25 (16)° in molecule B. In molecule A, the dimethylbenzene ring forms dihedral angles of 89.65 (8) and 42.98 (11)° with the two benzene rings, whereas the corresponding angles are equal to 63.15 (7) and 58.67 (10)° in molecule B. An intramolecular C—H⋯O hydrogen bond generates an S(6) ring motif in each molecule. In the crystal, molecules are linked by bifurcated (N,C)—H⋯O hydrogen bonds, generating R (2) (1)(6) ring motifs and forming infinite chains along the a axis. The crystal is further stabilized by C—H⋯π and π–π interactions with centroid–centroid distances of 3.8543 (18) and 3.930 (2) Å. |
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